Peroxidase-like activity of FeVO4 nanobelts and its analytical application for optical detection of hydrogen peroxide | |
Yu, Yanzhen1; Ju, Peng2,3; Zhang, Dun4; Han, Xiuxun2,3; Yin, Xiaofei1; Zheng, Li1,5; Sun, Chengjun1,6 | |
刊名 | SENSORS AND ACTUATORS B-CHEMICAL
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2016-10-05 | |
卷号 | 233页码:162-172 |
关键词 | FeVO4 nanobelts Peroxidase-like activity Optical determination Hydrogen peroxide |
ISSN号 | 0925-4005 |
DOI | 10.1016/j.snb.2016.04.041 |
英文摘要 | In this paper, FeVO4 materials were prepared via a facile hydrothermal method under different pHs and developed as highly efficient biomimetic catalysts for the first time. Different FeVO4 materials with different crystal structures, morphologies and surface properties showed distinct peroxidase-like activities. Experimental results showed that the products obtained at pH = 4 (FeVO4-4) possessed a belt-like nano-structure with a large BET specific surface area and exhibited the best intrinsic peroxidase-like activity compared to other FeVO4 materials. FeVO4-4 nanobelts (NBs) could efficiently catalyze the oxidation of 3,3',5,5'-tetramethylbenzidine (TMB) in the presence of H2O2 to generate a blue oxide. Based on the highly efficient catalytic activity of FeVO4-4 NBs, a novel system for optical determination of H2O2 was successfully established, and the detection limit of H2O2 could reach 0.2 mu M. FeVO4-4 NBs also exhibited excellent selectivity, reproducibility, long-term stability, and easy recovery property. Furthermore, a peroxidase mimetic mechanism of FeVO4-4 NBs was proposed based on the active species trapping experiments. This work developed a novel, accessible and highly sensitive system for visual detection of H2O2, making FeVO4-4 NBs a potential biomimetic catalysts in H2O2 detection and biomedical analysis. (C) 2016 Elsevier B.V. All rights reserved. |
资助项目 | CAS-Japan Society for the Promotion of Science (JSPS) Collaborative Research Program[GJHZ1317] |
WOS关键词 | COLORIMETRIC DETECTION ; HORSERADISH-PEROXIDASE ; CATALYTIC-ACTIVITY ; GLUCOSE DETECTION ; MAGNETIC NANOPARTICLES ; ARTIFICIAL ENZYMES ; VISUAL DETECTION ; H2O2 ; MIMETICS ; NANOSHEETS |
WOS研究方向 | Chemistry ; Electrochemistry ; Instruments & Instrumentation |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE SA |
WOS记录号 | WOS:000386830200005 |
内容类型 | 期刊论文 |
源URL | [http://ir.fio.com.cn:8080/handle/2SI8HI0U/27398] ![]() |
专题 | 自然资源部第一海洋研究所 |
通讯作者 | Han, Xiuxun; Sun, Chengjun |
作者单位 | 1.First Inst Oceanog State Ocean Adm, Marine Ecol Ctr, 6 Xianxialing Rd, Qingdao 266061, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lab Clean Energy Chem & Mat, 18 Tianshui Middle Rd, Lanzhou 730000, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, Qingdao Ctr Resource Chem & New Mat, 36 Jinshui Rd, Qingdao 266100, Peoples R China 4.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, 7 Nanhai Rd, Qingdao 266071, Peoples R China 5.Qingdao Natl Lab Marine Sci & Technol, Lab Marine Ecol & Environm Sci, Qingdao 266071, Peoples R China 6.Qingdao Natl Lab Marine Sci & Technol, Lab Marine Drugs & Bioprod, Qingdao 266071, Peoples R China |
推荐引用方式 GB/T 7714 | Yu, Yanzhen,Ju, Peng,Zhang, Dun,et al. Peroxidase-like activity of FeVO4 nanobelts and its analytical application for optical detection of hydrogen peroxide[J]. SENSORS AND ACTUATORS B-CHEMICAL,2016,233:162-172. |
APA | Yu, Yanzhen.,Ju, Peng.,Zhang, Dun.,Han, Xiuxun.,Yin, Xiaofei.,...&Sun, Chengjun.(2016).Peroxidase-like activity of FeVO4 nanobelts and its analytical application for optical detection of hydrogen peroxide.SENSORS AND ACTUATORS B-CHEMICAL,233,162-172. |
MLA | Yu, Yanzhen,et al."Peroxidase-like activity of FeVO4 nanobelts and its analytical application for optical detection of hydrogen peroxide".SENSORS AND ACTUATORS B-CHEMICAL 233(2016):162-172. |
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