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	New Usage for Cyclotrimerization Reaction: a Facile Synthesis of 1,3,5-Triazine Derivatives
	Ouyang, Mi1; Yu, Chun-hui1; Zhang, Ning-yu2; Song, Qing-bao1; Sun, Jing-wei1; Hu, Bin1; Zhang, Cheng1
	2013
关键词	1,3,5-Triazine Steric hindrance Different peripherals Electron-injection ability
卷号	531-532
DOI	10.4028/www.scientific.net/KEM.531-532.32
页码	32-+
英文摘要	Series of star-shaped molecules based on 1,3,5-triazine core have been synthesized via CF3SO3H-mediated cyclotrimerization reaction, and then characterized by H-1-NMR, C-13-NMR, MALDI-TOF-MS, and elemental analysis. The effects of different factors, such as the steric hindrance and electronegativity on the reaction efficiency, are systematically studied. The results indicate that the steric hindrance plays an important role in the reaction, while electronegativity has little impact on this reaction. In addition, the bridges including ethylene group and carbon atom between 1,3,5-triazine core and peripherals are firstly studied in this work, which expands the application of CF3SO3H-mediated cyclotrimerization reaction. Moreover, we have successfully broadened the cyclotrimerization reaction to the preparation of 1,3,5-triazine derivatives with different substituents as the peripheral, which is promising for preparation of single-layer multi-functional optoelectronic materials.
会议录出版者	TRANS TECH PUBLICATIONS LTD
会议录出版地	KREUZSTRASSE 10, 8635 DURNTEN-ZURICH, SWITZERLAND
语种	英语
WOS研究方向	Science & Technology - Other Topics ; Materials Science
WOS记录号	WOS:000316642300007
内容类型	会议论文
源URL	[http://10.2.47.112/handle/2XS4QKH4/3416]
专题	上海财经大学
作者单位	1.Zhejiang Univ Technol, State Key Lab Breeding Base Green Chem Synth Tech, Coll Chem Engn & Mat Sci, Chaowang Rd 18, Hangzhou 310014, Zhejiang, Peoples R China; 2.Shanghai Univ Finance & Econ, Econ Coll, Shanghai, Peoples R China
推荐引用方式 GB/T 7714	Ouyang, Mi,Yu, Chun-hui,Zhang, Ning-yu,et al. New Usage for Cyclotrimerization Reaction: a Facile Synthesis of 1,3,5-Triazine Derivatives[C]. 见:.

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