Double UV polymerisation with variable temperature-controllable selective reflection of polymer-stabilised liquid crystal (PSLC) composites | |
Xiao, Ling ; Cao, Hui ; Sun, Jian ; Wang, Huihui ; Wang, Dong ; Yang, Zhou ; He, Wanli ; Xiao, Jiumei ; Ding, Hangjun ; Yang, Huai | |
刊名 | LIQUID CRYSTALS
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2016 | |
关键词 | Liquid crystal selective reflection UV-radical polymerisation UV-cationic polymerisation non-uniform pitch distribution ELECTROOPTICAL PROPERTIES CHOLESTERIC TEXTURE LIGHT-REFLECTION BAND REFLECTION FILMS POLARIZERS PERFORMANCE DIFFUSION COATINGS |
DOI | 10.1080/02678292.2016.1172351 |
英文摘要 | In this study, a method of preparing wide-band reflection cholesteric liquid crystals (CLCs) films by UV-radical polymerisation in combination with UV-cationic polymerisation is proposed. Because the helical twisting power (HTP) of the chiral dopant decreases with increasing temperature and the polymerisation rate of UV-initiated free radical polymerisation is faster than UV-initiated cationic polymerisation, by adjusting the temperature, broadband reflective films with non-uniform pitch distribution are obtained. The fractured surface of the polymer network of the broadband reflective films is observed by scanning electron microscopy (SEM), which reveals the presence of non-uniform pitch distribution. In addition, the influences of monomer concentration, UV light intensity and UV curing time on the consequent non-uniform pitch distribution have been studied. [GRAPHICS]; National Natural Science Foundation of China [51473020, 51203011, 51173017, 51373024, 61370048, 51272026, 51273022]; Fundamental Research Funds for the Central Universities [FRF-TP-14-001A2]; Beijing Higher Education Young Elite Teacher Project [YETP0356]; SCI(E); ARTICLE; caohui@mater.ustb.edu.cn; yanghuai@pku.edu.cn; 10; 1299-1306; 43 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/492486] ![]() |
专题 | 工学院 |
推荐引用方式 GB/T 7714 | Xiao, Ling,Cao, Hui,Sun, Jian,et al. Double UV polymerisation with variable temperature-controllable selective reflection of polymer-stabilised liquid crystal (PSLC) composites[J]. LIQUID CRYSTALS,2016. |
APA | Xiao, Ling.,Cao, Hui.,Sun, Jian.,Wang, Huihui.,Wang, Dong.,...&Yang, Huai.(2016).Double UV polymerisation with variable temperature-controllable selective reflection of polymer-stabilised liquid crystal (PSLC) composites.LIQUID CRYSTALS. |
MLA | Xiao, Ling,et al."Double UV polymerisation with variable temperature-controllable selective reflection of polymer-stabilised liquid crystal (PSLC) composites".LIQUID CRYSTALS (2016). |
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