Controlled synthesis of concave cuboctahedral nitrogen-rich   metal-organic framework nanoparticles showing enhanced catalytic   activation of epoxides with carbon dioxide

doi:10.1039/c5ce01843a

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	Controlled synthesis of concave cuboctahedral nitrogen-rich metal-organic framework nanoparticles showing enhanced catalytic activation of epoxides with carbon dioxide
	Han, Xiguang ; Wang, Xiao-Jun ; Li, Pei-Zhou ; Zou, Ruqiang ; Li, Menghuan ; Zhao, Yanli
刊名	CRYSTENGCOMM
	2015
关键词	HIGH-INDEX FACETS ZEOLITIC IMIDAZOLATE FRAMEWORK-8 COORDINATION POLYMER PLATINUM NANOCRYSTALS CYCLIC CARBONATES SURFACE-AREA CO2 ADSORPTION CYCLOADDITION MORPHOLOGY
DOI	10.1039/c5ce01843a
英文摘要	Nitrogen-rich metal-organic framework (N-MOF) nanoparticles with an unusual concave cuboctahedral morphology were prepared through a facile wet-chemical route using benzimidazole as the modulator. Benzimidazole plays an essential role in controlling the concave cuboctahedral morphology of the nanoparticles. By changing the benzimidazole dosage, the resultant morphology can be tuned from a concave octahedron to a concave cuboctahedron. The concave cuboctahedral nanoparticles exhibit high catalytic efficiency for the activation of epoxides with carbon dioxide.; National Research Foundation (NRF), Prime Minister's Office, Singapore under its Campus for Research Excellence and Technological Enterprise (CREATE) Programme-Singapore Peking University Research Centre for a Sustainable Low-Carbon Future; NTU-A*Star Silicon Technologies Centre of Excellence [11235100003]; NSFC [21302072, 21201088]; NSF [BK20130226]; SCI(E); ARTICLE; rzou@pku.edu.cn; zhaoyanli@ntu.edu.sg; 45; 8596-8601; 17
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/439542]
专题	工学院
推荐引用方式 GB/T 7714	Han, Xiguang,Wang, Xiao-Jun,Li, Pei-Zhou,et al. Controlled synthesis of concave cuboctahedral nitrogen-rich metal-organic framework nanoparticles showing enhanced catalytic activation of epoxides with carbon dioxide[J]. CRYSTENGCOMM,2015.
APA	Han, Xiguang,Wang, Xiao-Jun,Li, Pei-Zhou,Zou, Ruqiang,Li, Menghuan,&Zhao, Yanli.(2015).Controlled synthesis of concave cuboctahedral nitrogen-rich metal-organic framework nanoparticles showing enhanced catalytic activation of epoxides with carbon dioxide.CRYSTENGCOMM.
MLA	Han, Xiguang,et al."Controlled synthesis of concave cuboctahedral nitrogen-rich metal-organic framework nanoparticles showing enhanced catalytic activation of epoxides with carbon dioxide".CRYSTENGCOMM (2015).