A highly thermal stable microporous lanthanide-organic framework for CO2 sorption and separation | |
Zhong, Ruiqin ; Yu, Xiaofeng ; Zou, Ruqiang | |
刊名 | INORGANIC CHEMISTRY COMMUNICATIONS
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2015 | |
关键词 | Lanthanide-organic framework Thermal stability CO2 adsorption Gas separation SECONDARY BUILDING UNITS COORDINATION POLYMERS ADSORPTION SELECTIVITY MAGNETIC-PROPERTIES CRYSTAL-STRUCTURES ISORETICULAR MOFS CARBON-DIOXIDE PORE-SIZE LUMINESCENCE CLUSTER |
DOI | 10.1016/j.inoche.2015.09.019 |
英文摘要 | A new lanthanide-organic framework formulated as TbL 1 (H3L = 9-(4-carboxy-phenyl)-9H-carbazole-3,6-dicarboxylic acid), was synthesized under hydrothermal reaction condition. Single-crystal X-ray diffraction analysis shows that 1 crystallizes in a hexagonal P6(5) space group with three-dimensional network and microporous structure. The desolventized framework of I shows much higher uptake of CO2 (43.7 cm(3) g(-1)) than that of CH4 (15.1 cm(3) g(-1)) at 1 atm and 273 K, which makes it a potential candidate for CO2/CH4 separation. (C) 2015 Elsevier B.V. All rights reserved.; NSFC [21203249]; Science Foundation of China University of Petroleum, Beijing [01JB0229]; SCI(E); ARTICLE; rzou@pku.edu.cn; 173-176; 61 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/439319] ![]() |
专题 | 工学院 |
推荐引用方式 GB/T 7714 | Zhong, Ruiqin,Yu, Xiaofeng,Zou, Ruqiang. A highly thermal stable microporous lanthanide-organic framework for CO2 sorption and separation[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2015. |
APA | Zhong, Ruiqin,Yu, Xiaofeng,&Zou, Ruqiang.(2015).A highly thermal stable microporous lanthanide-organic framework for CO2 sorption and separation.INORGANIC CHEMISTRY COMMUNICATIONS. |
MLA | Zhong, Ruiqin,et al."A highly thermal stable microporous lanthanide-organic framework for CO2 sorption and separation".INORGANIC CHEMISTRY COMMUNICATIONS (2015). |
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