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A highly thermal stable microporous lanthanide-organic framework for CO2 sorption and separation
Zhong, Ruiqin ; Yu, Xiaofeng ; Zou, Ruqiang
刊名INORGANIC CHEMISTRY COMMUNICATIONS
2015
关键词Lanthanide-organic framework Thermal stability CO2 adsorption Gas separation SECONDARY BUILDING UNITS COORDINATION POLYMERS ADSORPTION SELECTIVITY MAGNETIC-PROPERTIES CRYSTAL-STRUCTURES ISORETICULAR MOFS CARBON-DIOXIDE PORE-SIZE LUMINESCENCE CLUSTER
DOI10.1016/j.inoche.2015.09.019
英文摘要A new lanthanide-organic framework formulated as TbL 1 (H3L = 9-(4-carboxy-phenyl)-9H-carbazole-3,6-dicarboxylic acid), was synthesized under hydrothermal reaction condition. Single-crystal X-ray diffraction analysis shows that 1 crystallizes in a hexagonal P6(5) space group with three-dimensional network and microporous structure. The desolventized framework of I shows much higher uptake of CO2 (43.7 cm(3) g(-1)) than that of CH4 (15.1 cm(3) g(-1)) at 1 atm and 273 K, which makes it a potential candidate for CO2/CH4 separation. (C) 2015 Elsevier B.V. All rights reserved.; NSFC [21203249]; Science Foundation of China University of Petroleum, Beijing [01JB0229]; SCI(E); ARTICLE; rzou@pku.edu.cn; 173-176; 61
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/439319]  
专题工学院
推荐引用方式
GB/T 7714
Zhong, Ruiqin,Yu, Xiaofeng,Zou, Ruqiang. A highly thermal stable microporous lanthanide-organic framework for CO2 sorption and separation[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2015.
APA Zhong, Ruiqin,Yu, Xiaofeng,&Zou, Ruqiang.(2015).A highly thermal stable microporous lanthanide-organic framework for CO2 sorption and separation.INORGANIC CHEMISTRY COMMUNICATIONS.
MLA Zhong, Ruiqin,et al."A highly thermal stable microporous lanthanide-organic framework for CO2 sorption and separation".INORGANIC CHEMISTRY COMMUNICATIONS (2015).
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