Effects of Donor and Acceptor on Optoelectronic Performance for   Porphyrin Derivatives: Nonlinear Optical Properties and Dye-sensitized   Solar Cells

doi:10.1007/s40242-015-5241-9

CORC > 北京大学 > 工学院

	Effects of Donor and Acceptor on Optoelectronic Performance for Porphyrin Derivatives: Nonlinear Optical Properties and Dye-sensitized Solar Cells
	Mi Yongsheng ; Liang Pengxia ; Yang Zhou ; Wang Dong ; Cao Hui ; He Wanli ; Yang Huai
刊名	CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
	2015
关键词	Porphyrin derivative Click chemistry Optoelectronic performance Nonlinear optical property Dye-sensitized solar cell CHARGE-TRANSFER DYNAMICS ABSORPTION DESIGN STATE REFRACTION COMPLEXES DYADS
DOI	10.1007/s40242-015-5241-9
英文摘要	Typical asymmetric donor-x-bridge-acceptor(D-pi-A) zinc porphyrin dyes have been synthesized, and further modified by reacting the ethynyl groups of them with click reagent through a formal [2+2] click reaction. The electronic interaction between the push and pull electronic groups and the click reaction process were investigated by UV-Vis absorption spectroscopy. The nonlinear optical(NLO) properties of the dyes were studied by the Z-scan technique and clearly reverse saturable absorption to saturable absorption(RSA-SA) transition could be observed through click reaction of the dyes with TCNE. Furthermore, the photovoltaic properties of these porphyrin dyes were reasonably explained by the J-V curve fitting based on the equivalent-circuit model as well as the comparison between the absorption and incident-photon-to-current-conversion efficiency(IPCE) spectra. Besides, these dyes with different donors or acceptors could self-assembly into different microstructures by phase transfer methodology.; Supported by the Major Project of International Cooperation of the Ministry of Science and Technology, China,the National Natural Science Foundation of China,the Beijing Higher Education Young Elite Teacher Project, China,the Fundamental Research Funds for the Central Universities of China; SCI(E); 中国科技核心期刊(ISTIC); 中国科学引文数据库(CSCD); ARTICLE; yangz@ustb.edu.cn; wangdong@ustb.edu.cn; 6; 992-996; 31
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/439152]
专题	工学院
推荐引用方式 GB/T 7714	Mi Yongsheng,Liang Pengxia,Yang Zhou,et al. Effects of Donor and Acceptor on Optoelectronic Performance for Porphyrin Derivatives: Nonlinear Optical Properties and Dye-sensitized Solar Cells[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2015.
APA	Mi Yongsheng.,Liang Pengxia.,Yang Zhou.,Wang Dong.,Cao Hui.,...&Yang Huai.(2015).Effects of Donor and Acceptor on Optoelectronic Performance for Porphyrin Derivatives: Nonlinear Optical Properties and Dye-sensitized Solar Cells.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES.
MLA	Mi Yongsheng,et al."Effects of Donor and Acceptor on Optoelectronic Performance for Porphyrin Derivatives: Nonlinear Optical Properties and Dye-sensitized Solar Cells".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES (2015).