Scalable synthesis of ultrasmall SnO2 nanocrystals in carbon conductive matrices: High loading and excellent electrochemical performance | |
Qu, Jie ; Yang, Yongan ; Shi, Xiaomin ; Wang, Wei ; Ding, Jianning ; Yuan, Ningyi ; Zhao, Xinsheng ; Lai, Chao | |
刊名 | JOURNAL OF ALLOYS AND COMPOUNDS |
2016 | |
关键词 | Lithium-ion batteries Ultrasmall SnO2 Carbon High-rate performance High loading LITHIUM-ION BATTERIES CAPACITY ANODE MATERIAL SNO2/CARBON COMPOSITE SULFUR BATTERIES OXIDE COMPOSITE AMORPHOUS OXIDE RATE CAPABILITY BINDER-FREE STORAGE SHELL |
DOI | 10.1016/j.jallcom.2016.06.007 |
英文摘要 | Ultrasmall sub-5 nm SnO2 nanocrystals/carbon composites, with the SnO2 loading as high as 87.3 wt%, are synthesized via a facile hydrothermal route, followed by calcination. The annealed SnO2/C composite shows a higher discharge capacity and superior rate performance, compared with the pristine SnO2/C sample. At the current density of 200 mA g(-1), it can deliver a high reversible capacity of 968 mAh g(-1). When the current density increases to 5000 mA g(-1), a high discharge capacity of 435 mAh g(-1) can still be obtained, much higher than the theoretical capacity of graphite. Our results indicate the potential suitability of synthesizing ultrasmall electrode nanocrystals with high electrochemical performance. (C) 2016 Elsevier B.V. All rights reserved.; National Natural Science Foundation of China [21301022, 21376113]; Colorado School of Mines; SCI(E); EI; ARTICLE; wwang_bj@126.com; xinshengzhao@jsnu.edu.cn; 122-129; 686 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/437013] |
专题 | 工学院 |
推荐引用方式 GB/T 7714 | Qu, Jie,Yang, Yongan,Shi, Xiaomin,et al. Scalable synthesis of ultrasmall SnO2 nanocrystals in carbon conductive matrices: High loading and excellent electrochemical performance[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2016. |
APA | Qu, Jie.,Yang, Yongan.,Shi, Xiaomin.,Wang, Wei.,Ding, Jianning.,...&Lai, Chao.(2016).Scalable synthesis of ultrasmall SnO2 nanocrystals in carbon conductive matrices: High loading and excellent electrochemical performance.JOURNAL OF ALLOYS AND COMPOUNDS. |
MLA | Qu, Jie,et al."Scalable synthesis of ultrasmall SnO2 nanocrystals in carbon conductive matrices: High loading and excellent electrochemical performance".JOURNAL OF ALLOYS AND COMPOUNDS (2016). |
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