A study on the synthesis, characterization and properties of polyaniline nanofibers using ferric chloride as both oxidant and dopant | |
Ding, Hang Jun ; Yang, Zhou ; Yang, Huai ; Wan, Mei Xiang | |
2013 | |
DOI | 10.4028/www.scientific.net/AMR.807-809.2757 |
英文摘要 | PANI nanofibers with a really nano-scaled diameter of 20 ~ 30 nm and a high conductivity of 100 S/cm were successfully prepared by using FeCl3 · 6H2O as oxidant at the acidic dopant-free. Compared with other synthetic methods for nanostructures, this approach is most simple and cheap because of FeCl3 · 6H2O having two-function of oxidant and dopant at the same time, resulting in further simplifying reaction reagents. Characterizations of UV-visible, FTIR spectra, XRD as well as conductivity measured by four-probe method definitely proved the nanofibers oxidized by FeCl3 as oxidant at dopant-free are identical to the emeraldine salt form of PANI, although without external acidic dopant, and Cl anion is incorporated the PANI main chain as counter-ion. ? (2013) Trans Tech Publications, Switzerland.; EI; 0 |
语种 | 英语 |
内容类型 | 会议论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/411637] ![]() |
专题 | 工学院 |
推荐引用方式 GB/T 7714 | Ding, Hang Jun,Yang, Zhou,Yang, Huai,et al. A study on the synthesis, characterization and properties of polyaniline nanofibers using ferric chloride as both oxidant and dopant[C]. 见:. |
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