Comparison of additive amount used in spin-coated and roll-coated organic solar cells | |
Cheng, Pei ; Lin, Yuze ; Zawacka, Natalia K. ; Andersen, Thomas R. ; Liu, Wenqing ; Bundgaard, Eva ; Jorgensen, Mikkel ; Chen, Hongzheng ; Krebs, Frederik C. ; Zhan, Xiaowei | |
刊名 | journal of materials chemistry a |
2014 | |
关键词 | BULK-HETEROJUNCTION HIGH-PERFORMANCE EFFICIENCY ENHANCEMENT PHOTOVOLTAIC POLYMERS SOLVENT ADDITIVES SELF-ORGANIZATION DEVICE EFFICIENCY SMALL MOLECULES ACTIVE LAYERS SIDE-CHAINS |
DOI | 10.1039/c4ta04906c |
英文摘要 | All-polymer and polymer/fullerene inverted solar cells were fabricated by spin-coating and roll-coating processes. The spin-coated small-area (0.04 cm(2)) devices were fabricated on indium tin oxide (ITO) coated glass substrates in nitrogen. The roll-coated large-area (1.0 cm(2)) devices were prepared on ITO-free flexible substrates under ambient conditions. The use of a solvent additive, 1,8-diiodooctane (DIO), facilitated phase separation and enhanced power conversion efficiencies (PCEs). The PCE of polymer/fullerene solar cells increased from 4.58% to 8.12% with 2.5% (v/v) DIO when using the spin-coating process, and increased from 1.37% to 2.09% with 5% (v/v) DIO in the roll-coating process. The PCE of all-polymer solar cells increased from 1.44% to 3.51% with 4% (v/v) DIO when employing the spin-coating process. For the roll-coated large area devices the PCE increased from 0.15% to 0.73% with 9% (v/v) DIO. The optimal amounts of DIO, when using the roll-coating process for the two different active layers (5% and 9% respectively) are significantly higher than those for the spin-coating process (2.5% and 4%, respectively), which is ascribed to a fundamentally different drying mechanism.; Chemistry, Physical; Energy & Fuels; Materials Science, Multidisciplinary; SCI(E); 1; ARTICLE; xwzhan@pku.edu.cn; frkr@dtu.dk; 45; 19542-19549; 2 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/217230] |
专题 | 工学院 |
推荐引用方式 GB/T 7714 | Cheng, Pei,Lin, Yuze,Zawacka, Natalia K.,et al. Comparison of additive amount used in spin-coated and roll-coated organic solar cells[J]. journal of materials chemistry a,2014. |
APA | Cheng, Pei.,Lin, Yuze.,Zawacka, Natalia K..,Andersen, Thomas R..,Liu, Wenqing.,...&Zhan, Xiaowei.(2014).Comparison of additive amount used in spin-coated and roll-coated organic solar cells.journal of materials chemistry a. |
MLA | Cheng, Pei,et al."Comparison of additive amount used in spin-coated and roll-coated organic solar cells".journal of materials chemistry a (2014). |
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