Covalent Organic Frameworks Formed with Two Types of Covalent Bonds Based on Orthogonal Reactions | |
Zeng, Yongfei ; Zou, Ruyi ; Luo, Zhong ; Zhang, Huacheng ; Yao, Xin ; Ma, Xing ; Zou, Ruqiang ; Zhao, Yanli | |
刊名 | journal of the american chemical society
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2015 | |
关键词 | DESIGNED SYNTHESIS TARGETED SYNTHESIS CRYSTALLINE HYDROGEN COORDINATION CONSTRUCTION MACROCYCLES CHEMISTRY CATALYSIS POLYMERS |
DOI | 10.1021/ja510926w |
英文摘要 | Covalent organic frameworks (COFs) are excellent candidates for various applications. So far, successful methods for the constructions of COFs have been limited to a few condensation reactions based on only one type of covalent bond formation. Thus, the exploration of a new judicious synthetic strategy is a crucial and emergent task for the development of this promising class of porous materials. Here, we report a new orthogonal reaction strategy to construct COFs by reversible formations of two types of covalent bonds. The obtained COFs consisting of multiple components show high surface area and high H-2 adsorption capacity. The strategy is a general protocol applicable to construct not only binary COFs but also more complicated systems in which employing regular synthetic methods did not work.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000348690100004&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Multidisciplinary; SCI(E); EI; 30; ARTICLE; rzou@pku.edu.cn; zhaoyanli@ntu.edu.sg; 3; 1020-1023; 137 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/206250] ![]() |
专题 | 工学院 |
推荐引用方式 GB/T 7714 | Zeng, Yongfei,Zou, Ruyi,Luo, Zhong,et al. Covalent Organic Frameworks Formed with Two Types of Covalent Bonds Based on Orthogonal Reactions[J]. journal of the american chemical society,2015. |
APA | Zeng, Yongfei.,Zou, Ruyi.,Luo, Zhong.,Zhang, Huacheng.,Yao, Xin.,...&Zhao, Yanli.(2015).Covalent Organic Frameworks Formed with Two Types of Covalent Bonds Based on Orthogonal Reactions.journal of the american chemical society. |
MLA | Zeng, Yongfei,et al."Covalent Organic Frameworks Formed with Two Types of Covalent Bonds Based on Orthogonal Reactions".journal of the american chemical society (2015). |
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