Effects of Fe2O3 and ZnO nanoparticles on 17 beta-estradiol adsorption   to carbon nanotubes

doi:10.1016/j.cej.2017.05.007

CORC > 北京大学 > 环境科学与工程学院

	Effects of Fe2O3 and ZnO nanoparticles on 17 beta-estradiol adsorption to carbon nanotubes
	Shi, Wanzi ; Li, Si ; Chen, Ben ; Wang, Conghe ; Sun, Weiling
刊名	CHEMICAL ENGINEERING JOURNAL
	2017
关键词	Adsorption Carbon nanotubes Fe2O3 nanoparticles ZnO nanoparticles 17 beta-estradiol NATURAL ORGANIC-MATTER HIGH-RESOLUTION XPS INORGANIC NANOPARTICLES SOLUTION CHEMISTRY FUNCTIONAL-GROUPS HUMIC-ACID AGGREGATION SULFAMETHOXAZOLE NANOMATERIALS KINETICS
DOI	10.1016/j.cej.2017.05.007
英文摘要	Diverse engineering nanoparticles (NPs) have found their way into the environment due to their extensive applications. The widespread occurrence of NPs may affect the fate of the coexisting pollutants and other types of NPs in natural waters. This study investigated the heteroadsorption of pollutants to multiple NPs in simulated water environment. Particular attention was paid to the impact of two common metal oxide (MO) NPs, Fe2O3 and ZnO, on the adsorption of 17 beta-estradiol (E2) to carbon nanotubes (CNTs). The results showed that the presence of Fe2O3 and ZnO significantly increased the time to reach adsorption equilibrium for the adsorption of E2 to CNTs. The adsorption amount of E2 increased with increasing Fe2O3/CNTs ratio due to the adsorption of E2 to Fe2O3. In contrast, E2 adsorption was slightly inhibited by the presence of ZnO, resulting from the blockage of the adsorption sites on CNT surface by ZnO. DLVO theory calculation exhibited that Fe2O3 were likely to first homoaggregate and then heteroaggregate with CNTs, whereas the electrostatic attraction between oppositely charged ZnO and CNTs favored their heteroaggregation in the heterogeneous systems of CNTs and ZnO. This was confirmed by the transmission electron microscopy images and the thermo-gravimetric analysis. The findings highlighted the significant effects of MO on the adsorption of organic compounds to CNTs, and also provided better understanding of the fate and transport of CNTs and organic contaminants in natural aquatic environments, where they inevitably coexist with MO. (C) 2017 Published by Elsevier B.V.; National Natural Science Foundation of China [51379009]; SCI(E); ARTICLE; 1134-1144; 326
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/470460]
专题	环境科学与工程学院
推荐引用方式 GB/T 7714	Shi, Wanzi,Li, Si,Chen, Ben,et al. Effects of Fe2O3 and ZnO nanoparticles on 17 beta-estradiol adsorption to carbon nanotubes[J]. CHEMICAL ENGINEERING JOURNAL,2017.
APA	Shi, Wanzi,Li, Si,Chen, Ben,Wang, Conghe,&Sun, Weiling.(2017).Effects of Fe2O3 and ZnO nanoparticles on 17 beta-estradiol adsorption to carbon nanotubes.CHEMICAL ENGINEERING JOURNAL.
MLA	Shi, Wanzi,et al."Effects of Fe2O3 and ZnO nanoparticles on 17 beta-estradiol adsorption to carbon nanotubes".CHEMICAL ENGINEERING JOURNAL (2017).