Development of DNPH/HPLC method for the measurement of carbonyl   compounds in the aqueous phase: applications to laboratory simulation   and field measurement

doi:10.1071/EN09057

CORC > 北京大学 > 环境科学与工程学院

	Development of DNPH/HPLC method for the measurement of carbonyl compounds in the aqueous phase: applications to laboratory simulation and field measurement
	Wang, Hongli ; Zhang, Xuan ; Chen, Zhongming
刊名	环境化学
	2009
关键词	aqueous-phase atmosphere carbonyl DNPH/HPLC method SECONDARY ORGANIC AEROSOL AIR-WATER EXCHANGE OXIDATION-PRODUCTS LIQUID-CHROMATOGRAPHY VINYL KETONE GAS-PHASE CAPILLARY-ELECTROPHORESIS ATMOSPHERIC REACTIONS MASS-SPECTROMETRY RAIN WATER
DOI	10.1071/EN09057
英文摘要	The DNPH/HPLC method for characterising monocarbonyls and dicarbonyls in the aqueous phase has been developed. A series of experiments have been carried out using eight atmospheric ubiquitous carbonyl compounds as model dissolved compounds in both acetonitrile and water solution to obtain the optimal derivatisation and analysis qualifications. Compared with the analysis of carbonyls dissolved in acetonitrile, the influence of acidity on the derivatisation efficiency should be carefully considered in determining carbonyls in water and the optimal acidity is pH 2.0. We find that methyl vinyl ketone (MVK) transforms to crotonaldehyde during the derivatisation reaction. This transformation can be controlled to a minor degree by increasing the mixing ratio of DNPH to MVK up to 100 : 1. This improved method has been satisfactorily applied to laboratory simulations and field measurements for better understanding the carbonyl chemistry in the atmosphere.; Chemistry, Analytical; Environmental Sciences; SCI(E); 15; ARTICLE; 5; 389-397; 6
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/324485]
专题	环境科学与工程学院
推荐引用方式 GB/T 7714	Wang, Hongli,Zhang, Xuan,Chen, Zhongming. Development of DNPH/HPLC method for the measurement of carbonyl compounds in the aqueous phase: applications to laboratory simulation and field measurement[J]. 环境化学,2009.
APA	Wang, Hongli,Zhang, Xuan,&Chen, Zhongming.(2009).Development of DNPH/HPLC method for the measurement of carbonyl compounds in the aqueous phase: applications to laboratory simulation and field measurement.环境化学.
MLA	Wang, Hongli,et al."Development of DNPH/HPLC method for the measurement of carbonyl compounds in the aqueous phase: applications to laboratory simulation and field measurement".环境化学 (2009).