Modern and Fossil Contributions to Polycyclic Aromatic Hydrocarbons in   PM2.5 from North Birmingham, Alabama in the Southeastern U.S.

doi:10.1021/es2043189

CORC > 北京大学 > 环境科学与工程学院

	Modern and Fossil Contributions to Polycyclic Aromatic Hydrocarbons in PM2.5 from North Birmingham, Alabama in the Southeastern U.S.
	Xu, Li ; Zheng, Mei ; Ding, Xiang ; Edgerton, Eric S. ; Reddy, Christopher M.
刊名	environmental science technology
	2012
关键词	CHROMATOGRAPHY-MASS-SPECTROMETRY FINE PARTICULATE MATTER SOURCE APPORTIONMENT SOURCE IDENTIFICATION RADIOCARBON ANALYSIS AEROSOL RESEARCH UNITED-STATES COMBUSTION CARBON PAHS
DOI	10.1021/es2043189
英文摘要	Analyzing the radiocarbon (C-14) content of polycyclic aromatic hydrocarbons (PAHs) in atmospheric particulate matter can provide estimates on the source contributions from biomass burning versus fossil fuel. The relative importance of these two sources to ambient PAHs varies considerably across regions and even countries, and hence there is a pressing need to apportion these sources. In this study, we advanced the radiocarbon analysis from bulk carbon to compound class specific radiocarbon analysis (CCSRA) to determine Delta C-14 and delta C-13 values of PAHs in PM2.5 samples for investigating biomass burning and fossil fuel source contributions to PAHs from one of the Southeastern Aerosol Research and Characterization (SEARCH) sites in North Birmingham (BHM), Alabama during winter (December 2004-February 2005) and summer (June-August 2005) by accelerator mass spectrometry. To compare our ambient samples to known sources, we collected and analyzed fenceline samples from the vicinity of a coke plant in BHM. As expected, PAHs from the coke plant fenceline samples had very low radiocarbon levels. Its Delta C-14 varied from -990 to -970 parts per thousand, indicating that 97 to 99% were of fossil source. PAHs in the ambient PM2.5 had Delta C-14 from -968 to -911 parts per thousand, indicating that 92-97% of PAHs were from fossil fuel combustion. These levels indicated the dominance of fossil sources of ambient PAHs. The radiocarbon level of ambient PAHs was higher in winter than in summer. Winter samples exhibited depleted delta C-13 value and enriched Delta C-14 value because of the increased contribution of PAHs from biomass burning source. However, biomass burning contributed more to heavier PAHs (modern source accounting for 6-8%) than fighter ones with a modern contribution of 3%.; Engineering, Environmental; Environmental Sciences; SCI(E); EI; 6; ARTICLE; 3; 1422-1429; 46
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/234663]
专题	环境科学与工程学院
推荐引用方式 GB/T 7714	Xu, Li,Zheng, Mei,Ding, Xiang,et al. Modern and Fossil Contributions to Polycyclic Aromatic Hydrocarbons in PM2.5 from North Birmingham, Alabama in the Southeastern U.S.[J]. environmental science technology,2012.
APA	Xu, Li,Zheng, Mei,Ding, Xiang,Edgerton, Eric S.,&Reddy, Christopher M..(2012).Modern and Fossil Contributions to Polycyclic Aromatic Hydrocarbons in PM2.5 from North Birmingham, Alabama in the Southeastern U.S..environmental science technology.
MLA	Xu, Li,et al."Modern and Fossil Contributions to Polycyclic Aromatic Hydrocarbons in PM2.5 from North Birmingham, Alabama in the Southeastern U.S.".environmental science technology (2012).