Development and validation of a cryogen-free automatic gas chromatograph system (GC-MS/FID) for online measurements of volatile organic compounds | |
Wang, Ming ; Zeng, Limin ; Lu, Sihua ; Shao, Min ; Liu, Xinglong ; Yu, Xuena ; Chen, Wentai ; Yuan, Bin ; Zhang, Qian ; Hu, Min ; Zhang, Zhanyi | |
刊名 | analytical methods |
2014 | |
关键词 | REACTION MASS-SPECTROMETRY VOC MEASUREMENTS CHINA AIR HYDROCARBONS QUALITY HCHO |
DOI | 10.1039/c4ay01855a |
英文摘要 | An automatic gas chromatograph system equipped with a mass spectrometer and a flame ionization detector (GC-MS/FID) was developed for online measurements of volatile organic compounds (VOCs) in the atmosphere. This system consisted of a custom-built cryogen-free cooling device that can create an ultra-low temperature of -165 degrees C, a two-channel sampling and pre-concentration system, and a commercial GC-MS/FID. One channel in the sampling and pre-concentration system was designated to trap C2-C5 hydrocarbons, whereas the other was designed to trap other VOC species. The newly developed GC-MS/FID system was then employed to measure VOCs in ambient air, and its observation data were compared with those from three well-established techniques, including an offline GC-MS/FID coupled with canister sampling, a proton transfer reaction-mass spectrometer (PTR-MS), and an online gas chromatograph system equipped with an FID and a photo ionization detector (GC-FID/PID). The online and offline GC-MS/FID measurements for alkanes, acetylene, C2-C3 alkenes, C6-C8 aromatics, and halocarbons showed good agreement. In addition, the online GC-MS/FID measurements for C6-C9 aromatics, acetone, and methacrolein + methylvinylketone (MACR + MVK) agreed well with the PTR-MS observations. Mixing ratios of C2-C7 alkanes, C3-C5 alkenes, and C6-C8 aromatics also showed good agreement between the online GC-MS/FID and GC-FID/PID techniques. These inter-comparison results demonstrated the accuracy of online GC-MS/FID measurements for C2-C12 NMHCs, C3-C4 carbonyls, and halocarbons.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000344964700032&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Analytical; Food Science & Technology; Spectroscopy; SCI(E); EI; 6; ARTICLE; lmzeng@pku.edu.cn; mshao@pku.edu.cn; 23; 9424-9434; 6 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/158277] |
专题 | 环境科学与工程学院 |
推荐引用方式 GB/T 7714 | Wang, Ming,Zeng, Limin,Lu, Sihua,et al. Development and validation of a cryogen-free automatic gas chromatograph system (GC-MS/FID) for online measurements of volatile organic compounds[J]. analytical methods,2014. |
APA | Wang, Ming.,Zeng, Limin.,Lu, Sihua.,Shao, Min.,Liu, Xinglong.,...&Zhang, Zhanyi.(2014).Development and validation of a cryogen-free automatic gas chromatograph system (GC-MS/FID) for online measurements of volatile organic compounds.analytical methods. |
MLA | Wang, Ming,et al."Development and validation of a cryogen-free automatic gas chromatograph system (GC-MS/FID) for online measurements of volatile organic compounds".analytical methods (2014). |
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