Pressure-Induced Phase Transition of V203 | |
Zhang Qian ; Wu Xiang ; Qin Shan | |
刊名 | Chinese Physics Letters
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2012 | |
英文摘要 | In situ high pressure experiment of V_2O_3 is carried out by means of synchrotron radiation angle dispersive x-ray diffraction with the diamond anvil cell technique up to about 42 GPa at room temperature. A reversible phase transition unreported previously is observed at above 31 GPa. The c-axis compressibility of corundum-type V_2O_3 shows an abnormal behavior, i.e., the axial length increasing up to 9 GPa then decreasing at higher pressures, which could be attributed to the 3d electronic interaction. The results of compression for V_2O_3 are described by the second-order Birch-Murnaghan equation of state with V_0 = 300.2(4) A~3 and B_0 = 255(9) GPa.; Supported by the National Natural Science Foundation of China,Shanghai Synchrotron Radiation Facility; 中国科技核心期刊(ISTIC); 中国科学引文数据库(CSCD); 10; 106101-1-106101-3; 29 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/419064] ![]() |
专题 | 地球与空间科学学院 |
推荐引用方式 GB/T 7714 | Zhang Qian,Wu Xiang,Qin Shan. Pressure-Induced Phase Transition of V203[J]. Chinese Physics Letters,2012. |
APA | Zhang Qian,Wu Xiang,&Qin Shan.(2012).Pressure-Induced Phase Transition of V203.Chinese Physics Letters. |
MLA | Zhang Qian,et al."Pressure-Induced Phase Transition of V203".Chinese Physics Letters (2012). |
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