Study on a tetranuclear neodymium complex in polytrifluorochloroethylene oil for liquid lasers

CORC > 西安光学精密机械研究所 > 中国科学院西安光学精密机械研究所 > 瞬态光学技术国家重点实验室

	Study on a tetranuclear neodymium complex in polytrifluorochloroethylene oil for liquid lasers
	Qiu, Xiaoming 1; Yu, Kehan 1; Lu, Jiabao 1; Gao, Chao 2; Hou, Chaoqi2 ; He, Junfang 2; Wei, Wei 1; Peng, Bo 1,2
刊名	optical materials
	2008-10-01
卷号	31 期号:2 页码:117-121
关键词	Crystal structure Optical properties Lifetime Liquid laser
ISSN号	0925-3467
英文摘要	a liquid solution on the basis of dissolving a novel tetranuclear neodymium complex nd(4)(tta)(10)o(12)h(22) (htta: 2-thenoyltrifluoroacetone) in polytrifluorochloroethylene oil was presented. the molecular structure of the complex was characterized by single-crystal x-ray diffraction. the optical properties of the liquid medium were studied. enhanced emission was observed at 1064 nm when excited at 340 urn due to efficient energy transfer from t-fa to the nd(3+) ions and the mechanism for energy transfer process was discussed in detail. the obtained fluorescent lifetime was 1.7 mu s and the quantum yield value was 0.63%, which compare well with some other organic liquid media reported previously. besides, this liquid shows outstanding properties with no toxicity and causticity, nonvolatility and high stability. (c) 2008 elsevier b.v. all rights reserved.
学科主题	物理科学和化学
WOS标题词	science & technology ; technology ; physical sciences
类目[WOS]	materials science, multidisciplinary ; optics
研究领域[WOS]	materials science ; optics
关键词[WOS]	rare-earth ions ; radiationless transition ; lanthanide complexes ; optical-fiber ; luminescence ; glass ; nd ; relaxation ; emission ; ligands
收录类别	SCI ; EI
语种	英语
WOS记录号	WOS:000261822200001
公开日期	2011-09-30
内容类型	期刊论文
源URL	[http://ir.opt.ac.cn/handle/181661/11029]
专题	西安光学精密机械研究所_瞬态光学技术国家重点实验室
作者单位	1.Fudan Univ, State Key Lab Adv Photon Mat & Devices, Shanghai 200433, Peoples R China 2.Chinese Acad Sci, State Key Lab Transient Opt & Photon, Xian Inst Opt & Precis Mech, Xian 710119, Shaanxi, Peoples R China
推荐引用方式 GB/T 7714	Qiu, Xiaoming,Yu, Kehan,Lu, Jiabao,et al. Study on a tetranuclear neodymium complex in polytrifluorochloroethylene oil for liquid lasers[J]. optical materials,2008,31(2):117-121.
APA	Qiu, Xiaoming.,Yu, Kehan.,Lu, Jiabao.,Gao, Chao.,Hou, Chaoqi.,...&Peng, Bo.(2008).Study on a tetranuclear neodymium complex in polytrifluorochloroethylene oil for liquid lasers.optical materials,31(2),117-121.
MLA	Qiu, Xiaoming,et al."Study on a tetranuclear neodymium complex in polytrifluorochloroethylene oil for liquid lasers".optical materials 31.2(2008):117-121.