Structural characterization of the FeTiO3-MnTiO3 solid solution | |
Wu, Xiang ; Qin, Shan ; Dubrovinsky, Leonid | |
刊名 | journal of solid state chemistry
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2010 | |
关键词 | Ilmenite Solid solution X-ray diffraction Mossbauer spectroscopy Raman spectroscopy CRYSTAL-STRUCTURES PHASE-TRANSITION HIGH-PRESSURES ILMENITE FETIO3 TEMPERATURES PYROPHANITE DIFFRACTION SPECTRA MGGEO3 |
DOI | 10.1016/j.jssc.2010.08.020 |
英文摘要 | We have synthesized the (Mn1-xFe)TiO3 (0.0 <= x <= 1.0) solid solution compounds by high-temperature sintered methods, and characterized their crystal structures by combining X-ray diffraction, Mossbauer spectroscopy and Raman spectroscopy. Lattice constants and volumes show a linear decrease with increase in FeTiO3 content. All experimental results illustrate a decreasing distortion of TiO6 (or FeO6/MnO6) octahedra with increase in FeTiO3 content. The vibrational frequency of O-Ti-O bending motions presents a direct dependence on the corresponding bond angle (the angle O-Ti-O). Crown Copyright (C) 2010 Published by Elsevier Inc. All rights reserved.; Chemistry, Inorganic & Nuclear; Chemistry, Physical; SCI(E); EI; 3; ARTICLE; 10; 2483-2489; 183 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/155840] ![]() |
专题 | 地球与空间科学学院 |
推荐引用方式 GB/T 7714 | Wu, Xiang,Qin, Shan,Dubrovinsky, Leonid. Structural characterization of the FeTiO3-MnTiO3 solid solution[J]. journal of solid state chemistry,2010. |
APA | Wu, Xiang,Qin, Shan,&Dubrovinsky, Leonid.(2010).Structural characterization of the FeTiO3-MnTiO3 solid solution.journal of solid state chemistry. |
MLA | Wu, Xiang,et al."Structural characterization of the FeTiO3-MnTiO3 solid solution".journal of solid state chemistry (2010). |
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