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Enhanced photocurrent response on a CdTe incorporated coordination polymer based on 3-(3-(1H-imidazol-1-yl)phenyl)-5-(4-(1H-imidazol-1-yl)phenyl)-1-methyl-1 H-1,2,4-triazole
Meng, Jiang Ping ; Gong, Yun ; Lin, Jian Hua
刊名RSC ADVANCES
2016
关键词METAL-ORGANIC FRAMEWORKS THIN-FILM PHOTOVOLTAIC PERFORMANCE SOLAR-CELLS ELECTRODEPOSITION DEPOSITION ENERGY CHARGE WATER NANOSTRUCTURES
DOI10.1039/c6ra11641h
英文摘要By using a rigid N donor, 3-(3-(1H-imidazol-1-yl) phenyl)-5-(4-(1H-imidazol-1-yl) phenyl)-1-methyl-1H-1,2,4- triazole(L), two coordination polymers (CPs) formulated as Zn4L2(bpca)(4)center dot 4DMF center dot 9H(2)O (H(2)bpca = biphenyl-4,4'-dicarboxylic acid) (1) and Cd2L2(4,4'-cdba)(2)center dot 2DMF (4,4'-H(2)cdba = 4,4'-carbonyldibenzoic acid) (2) were solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction. CP 1 is a 2-fold interpenetrated uninodal 6-connected three-dimensional (3D) framework with a {4(12) center dot 6(3)}-pcu topology. CP 2 displays a uninodal 4-connected two-dimensional (2D) layer with a 4(4)-sql topology. The two CPs exhibit different electrochemical properties and photoelectrochemical behaviors. Their UV-vis spectra and band structures have been investigated. Meanwhile, CdTe and the CP 1@CdTe composite were synthesized by electrodeposition, and the CP 1@CdTe composite exhibits a much higher photocurrent density than CP 1 and CdTe.; National Natural Science Foundation of China [21371184]; large-scale instrument and equipment open foundation in Chongqing University [201606150053]; Chongqing Key Laboratory of Chemical Process for Clean Energy and Resource Utilization; Science and Technology Research Foundation of the Education Commission of Chongqing [KJ1501124]; SCI(E); EI; ARTICLE; gongyun7211@cqu.edu.cn; jhlin@pku.edu.cn; 77; 73869-73878; 6
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/494858]  
专题化学与分子工程学院
推荐引用方式
GB/T 7714
Meng, Jiang Ping,Gong, Yun,Lin, Jian Hua. Enhanced photocurrent response on a CdTe incorporated coordination polymer based on 3-(3-(1H-imidazol-1-yl)phenyl)-5-(4-(1H-imidazol-1-yl)phenyl)-1-methyl-1 H-1,2,4-triazole[J]. RSC ADVANCES,2016.
APA Meng, Jiang Ping,Gong, Yun,&Lin, Jian Hua.(2016).Enhanced photocurrent response on a CdTe incorporated coordination polymer based on 3-(3-(1H-imidazol-1-yl)phenyl)-5-(4-(1H-imidazol-1-yl)phenyl)-1-methyl-1 H-1,2,4-triazole.RSC ADVANCES.
MLA Meng, Jiang Ping,et al."Enhanced photocurrent response on a CdTe incorporated coordination polymer based on 3-(3-(1H-imidazol-1-yl)phenyl)-5-(4-(1H-imidazol-1-yl)phenyl)-1-methyl-1 H-1,2,4-triazole".RSC ADVANCES (2016).
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