Fullerene-Based Macro-Heterocycle Prepared through Selective Incorporation of Three N and Two O Atoms into C-60 | |
Li, Yanbang ; Zhang, Gaihong ; Wang, Dian ; Xu, Beidi ; Xu, Dan ; Lou, Ning ; Gan, Liangbing | |
刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
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2016 | |
关键词 | copper complex fullerenes guanidine heterocycles macrocycle OPEN-CAGE FULLERENES ARYLBORONIC ACIDS HETEROFULLERENES ENCAPSULATION ORIFICES PEROXIDE MOLECULE ANILINES HYDROGEN C58N2 |
DOI | 10.1002/anie.201606856 |
英文摘要 | A 14-membered heterocycle is created on the C-60 cage skeleton through a multistep procedure. Key steps involve repeated PCl5-induced hydroxylamino N-O bond cleavage leading to insertion of nitrogen atoms, and also piperidine-induced peroxo O-O bond cleavage leading to insertion of oxygen atoms. The hetero atoms form one pyrrole, two pyran, and one diazepine rings in conjunction with the C-60 skeleton carbon atoms. The fullerene-based macrocycle showed unique reactivities towards fluoride ion and copper salts.; NNSFC [21272013, 21132007]; MOST [2015CB856600]; SCI(E); PubMed; ARTICLE; gan@pku.edu.cn; 47; 14590-14594; 55 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/493165] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Li, Yanbang,Zhang, Gaihong,Wang, Dian,et al. Fullerene-Based Macro-Heterocycle Prepared through Selective Incorporation of Three N and Two O Atoms into C-60[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016. |
APA | Li, Yanbang.,Zhang, Gaihong.,Wang, Dian.,Xu, Beidi.,Xu, Dan.,...&Gan, Liangbing.(2016).Fullerene-Based Macro-Heterocycle Prepared through Selective Incorporation of Three N and Two O Atoms into C-60.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. |
MLA | Li, Yanbang,et al."Fullerene-Based Macro-Heterocycle Prepared through Selective Incorporation of Three N and Two O Atoms into C-60".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016). |
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