Fullerene-Based Macro-Heterocycle Prepared through Selective   Incorporation of Three N and Two O Atoms into C-60

doi:10.1002/anie.201606856

CORC > 北京大学 > 化学与分子工程学院

	Fullerene-Based Macro-Heterocycle Prepared through Selective Incorporation of Three N and Two O Atoms into C-60
	Li, Yanbang ; Zhang, Gaihong ; Wang, Dian ; Xu, Beidi ; Xu, Dan ; Lou, Ning ; Gan, Liangbing
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2016
关键词	copper complex fullerenes guanidine heterocycles macrocycle OPEN-CAGE FULLERENES ARYLBORONIC ACIDS HETEROFULLERENES ENCAPSULATION ORIFICES PEROXIDE MOLECULE ANILINES HYDROGEN C58N2
DOI	10.1002/anie.201606856
英文摘要	A 14-membered heterocycle is created on the C-60 cage skeleton through a multistep procedure. Key steps involve repeated PCl5-induced hydroxylamino N-O bond cleavage leading to insertion of nitrogen atoms, and also piperidine-induced peroxo O-O bond cleavage leading to insertion of oxygen atoms. The hetero atoms form one pyrrole, two pyran, and one diazepine rings in conjunction with the C-60 skeleton carbon atoms. The fullerene-based macrocycle showed unique reactivities towards fluoride ion and copper salts.; NNSFC [21272013, 21132007]; MOST [2015CB856600]; SCI(E); PubMed; ARTICLE; gan@pku.edu.cn; 47; 14590-14594; 55
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/493165]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Li, Yanbang,Zhang, Gaihong,Wang, Dian,et al. Fullerene-Based Macro-Heterocycle Prepared through Selective Incorporation of Three N and Two O Atoms into C-60[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016.
APA	Li, Yanbang.,Zhang, Gaihong.,Wang, Dian.,Xu, Beidi.,Xu, Dan.,...&Gan, Liangbing.(2016).Fullerene-Based Macro-Heterocycle Prepared through Selective Incorporation of Three N and Two O Atoms into C-60.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION.
MLA	Li, Yanbang,et al."Fullerene-Based Macro-Heterocycle Prepared through Selective Incorporation of Three N and Two O Atoms into C-60".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016).