Synthesis and Properties of [Cd(HTRTR)(2)(H2O)(4)](HTNR)(2) as an   Energetic Complex

doi:10.1002/zaac.201600101

CORC > 北京大学 > 化学与分子工程学院

	Synthesis and Properties of [Cd(HTRTR)(2)(H2O)(4)](HTNR)(2) as an Energetic Complex
	Chen, Sitong ; Guo, Weiming ; Bi, Yangang ; Zhang, Tonglai
刊名	ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
	2016
关键词	Energetic complex Crystal structure Thermal analysis Sensitivities Cadmium Calorimetry FLUORESCENT PROPERTIES CRYSTAL-STRUCTURE MONOMERIC ZN(II) BITRIAZOLE ASSEMBLIES LIGAND
DOI	10.1002/zaac.201600101
英文摘要	The energetic complex, [Cd(HTRTR)(2)(H2O)(4)](HTNR)(2) {HTRTR = 4-[3-(1,2,4-triazol-yl)-1,2,4-triaozle; HTNR- = styphnic acid anion) was synthesized and characterized by FT-IR spectroscopy, elemental analysis, and single-crystal X-ray diffraction. It crystallizes triclinic in space group P [a = 8.156(2) angstrom, b = 8.374(2) angstrom, c = 13.267(4) angstrom, = 84.925(11)degrees, = 87.016(11)degrees, = 63.683(5)degrees, V = 808.9(4) angstrom(3), = 1.940 gcm(-3)]. The Cd-II ion is six-coordinate with two HTRTRs and four water molecules. The thermal stabilities were investigated by differential scanning calorimetry (DSC). Non-isothermal reaction kinetic parameters were calculated by Kissinger's and Ozawa-Doyle's methods to obtain E-K = 144.0 kJmol(-1), lgA(K) = 14.22, and E-O = 144.3 kJmol(-1). The values of thermodynamic parameters, the peak temperature while 0 (T-p0), free energy of activation (G), entropy of activation (S), and enthalpy of activation (H) were obtained. Additionally, the enthalpy of formation was calculated by Hess's law on the basis of the experimental constant-volume heat of combustion measured by bomb calorimetry, obtaining H-f degrees(298) = 4985.5 kJmol(-1). Finally, the sensitivities toward impact and friction were assessed according to relevant methods. The result indicates it as an insensitive energetic material.; SCI(E); ARTICLE; ztlbit@bit.edu.cn; 13; 761-765; 642
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/492250]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Chen, Sitong,Guo, Weiming,Bi, Yangang,et al. Synthesis and Properties of [Cd(HTRTR)(2)(H2O)(4)](HTNR)(2) as an Energetic Complex[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2016.
APA	Chen, Sitong,Guo, Weiming,Bi, Yangang,&Zhang, Tonglai.(2016).Synthesis and Properties of [Cd(HTRTR)(2)(H2O)(4)](HTNR)(2) as an Energetic Complex.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE.
MLA	Chen, Sitong,et al."Synthesis and Properties of [Cd(HTRTR)(2)(H2O)(4)](HTNR)(2) as an Energetic Complex".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE (2016).