Two Magnetic Switching Complexes Based on the Fe-II Ion

doi:10.1021/acs.inorgchem.6b00258

CORC > 北京大学 > 化学与分子工程学院

	Two Magnetic Switching Complexes Based on the Fe-II Ion
	Yang, Qian ; Gao, Chen ; Wang, Ye-Xin ; Wang, Bing-Wu ; Wang, Zhe-Ming ; Gao, Song
刊名	INORGANIC CHEMISTRY
	2016
关键词	SPIN-CROSSOVER BEHAVIOR ROOM-TEMPERATURE TRANSITION MONONUCLEAR HYSTERESIS DISTORTION
DOI	10.1021/acs.inorgchem.6b00258
英文摘要	Two neutral mononuclear iron(II) complexes with different spin-crossover (SCO) properties, Fe(L1)(2)(SCN)(2) (1) and Fe(L2)(2)(SCN)(2) (2) (L1 = 2-(thiophen-3-yl)-1H-imidazo[4,5-f][1,10]phenanthroline and L2 = 2-(thiophen-2-yl)-1H-imidazo[4,5-f][1,10]phenanthroline), were solvothermally synthesized. With the different substituted position in 1,10-phenanthroline derivatives, 1 exhibits gradual SCO around room temperature with T-1/2 = 280 K, while 2 displays abrupt SCO with 10 K hysteresis at T-1/2 down arrow = 210 K and T-1/2 up arrow = 220 K.; Natural Science Foundation of China [21321001, 21290171, 21571008, 91422302]; National Basic Research Program [2013CB933401]; Beijing National Laboratory for Molecular Sciences Foundation; SCI(E); PubMed; ARTICLE; wangbw@pku.edu.cn; gaosong@pku.edu.cn; 16; 7805-7807; 55
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/491585]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Yang, Qian,Gao, Chen,Wang, Ye-Xin,et al. Two Magnetic Switching Complexes Based on the Fe-II Ion[J]. INORGANIC CHEMISTRY,2016.
APA	Yang, Qian,Gao, Chen,Wang, Ye-Xin,Wang, Bing-Wu,Wang, Zhe-Ming,&Gao, Song.(2016).Two Magnetic Switching Complexes Based on the Fe-II Ion.INORGANIC CHEMISTRY.
MLA	Yang, Qian,et al."Two Magnetic Switching Complexes Based on the Fe-II Ion".INORGANIC CHEMISTRY (2016).