An Imide-Based Pentacyclic Building Block for n-Type Organic   Semiconductors

doi:10.1002/chem.201703415

CORC > 北京大学 > 化学与分子工程学院

	An Imide-Based Pentacyclic Building Block for n-Type Organic Semiconductors
	Wu, Fu-Peng ; Un, Hio-leng ; Li, Yongxi ; Hu, Hailiang ; Yuan, Yi ; Yang, Bin ; Xiao, Kai ; Chen, Wei ; Wang, Jie-Yu ; Jiang, Zuo-Quan ; Pei, Jian ; Liao, Liang-Sheng
刊名	CHEMISTRY-A EUROPEAN JOURNAL
	2017
关键词	electron-deficiency fused rings imides organic semiconductors thiophenes POLYMER SOLAR-CELLS FIELD-EFFECT TRANSISTORS HIGH ELECTRON-AFFINITY CONJUGATED POLYMERS HIGH-PERFORMANCE PHOTOVOLTAIC PERFORMANCE MOBILITY ACCEPTOR DIIMIDES CHANNEL
DOI	10.1002/chem.201703415
英文摘要	A new electron-deficient unit with a fused 5-membered heterocyclic ring was developed by replacing a cyclopenta-1,3-diene from electron-rich donor indaceno-dithiophene (IDT) with a cyclohepta-4,6-diene-1,3-diimde unit. The imide bridge endows dithienylbenzenebisimide (BBI) with a fixed planar configuration and low energy levels for both the highest occupied molecular orbital (HOMO; -6.24 eV) and the lowest unoccupied molecular orbit (LUMO; -2.57 eV). Organic field-effect transistors (OFETs) based on BBI polymers exhibit electron mobility up to 0.34 cm(2) V-1 s(-1),which indicates that the BBI is a promising n-type building block for optoelectronics.; National Natural Science Foundation of China [21504062, 21572152]; China Postdoctoral Science Foundation [2015M581853]; US Department of Energy, Office of Science, Materials Sciences and Engineering Division; US Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]; SCI(E); ARTICLE; 59; 14723-14727; 23
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/484621]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Wu, Fu-Peng,Un, Hio-leng,Li, Yongxi,et al. An Imide-Based Pentacyclic Building Block for n-Type Organic Semiconductors[J]. CHEMISTRY-A EUROPEAN JOURNAL,2017.
APA	Wu, Fu-Peng.,Un, Hio-leng.,Li, Yongxi.,Hu, Hailiang.,Yuan, Yi.,...&Liao, Liang-Sheng.(2017).An Imide-Based Pentacyclic Building Block for n-Type Organic Semiconductors.CHEMISTRY-A EUROPEAN JOURNAL.
MLA	Wu, Fu-Peng,et al."An Imide-Based Pentacyclic Building Block for n-Type Organic Semiconductors".CHEMISTRY-A EUROPEAN JOURNAL (2017).