CRYSTAL STRUCTURE OF A REMARKABLE POLYMETALLATE OXYGEN CLUSTER[H_6Mo_(57)Fe_e~Ⅱ(NO)_(185)(H_2O)_(16)(MoO)_2]~(6-); CRYSTAL STRUCTURE OF A REMARKABLE POLYMETALLATE OXYGEN CLUSTER[H_6Mo_(57)Fe_e~Ⅱ(NO)_(185)(H_2O)_(16)(MoO)_2]~(6-) | |
1993 | |
关键词 | indication molybdenum vanadium Fe_e H_2O MoO NO valence remarkable challenge indication molybdenum vanadium Fe_e H_2O MoO NO valence remarkable challenge |
英文摘要 | Understanding the driving force for the formation of high nuclearity clusters is still a formidable challenge.We recently reported the structure with the largest polymetallate cluster involving mixed valence molybdenum and vanadium(Ⅳ) or iron(Ⅲ)(Zhang,Huang,Shao & Tang,J.Chem.Soc.,Chem.Commun.,(1993),1,37).Here is another remarkable cluster structure with mixed valence molybdenum and iron(Ⅱ).They may give an indication about the possible mechanism of formation of the polymolybdate.; Understanding the driving force for the formation of high nuclearity clusters is still a formidable challenge.We recently reported the structure with the largest polymetallate cluster involving mixed valence molybdenum and vanadium(Ⅳ) or iron(Ⅲ)(Zhang,Huang,Shao & Tang,J.Chem.Soc.,Chem.Commun.,(1993),1,37).Here is another remarkable cluster structure with mixed valence molybdenum and iron(Ⅱ).They may give an indication about the possible mechanism of formation of the polymolybdate.; IUCR; 1 |
语种 | 英语 |
内容类型 | 其他 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/479394] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | . CRYSTAL STRUCTURE OF A REMARKABLE POLYMETALLATE OXYGEN CLUSTER[H_6Mo_(57)Fe_e~Ⅱ(NO)_(185)(H_2O)_(16)(MoO)_2]~(6-), CRYSTAL STRUCTURE OF A REMARKABLE POLYMETALLATE OXYGEN CLUSTER[H_6Mo_(57)Fe_e~Ⅱ(NO)_(185)(H_2O)_(16)(MoO)_2]~(6-). 1993-01-01. |
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