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CRYSTAL STRUCTURE OF A REMARKABLE POLYMETALLATE OXYGEN CLUSTER[H_6Mo_(57)Fe_e~Ⅱ(NO)_(185)(H_2O)_(16)(MoO)_2]~(6-); CRYSTAL STRUCTURE OF A REMARKABLE POLYMETALLATE OXYGEN CLUSTER[H_6Mo_(57)Fe_e~Ⅱ(NO)_(185)(H_2O)_(16)(MoO)_2]~(6-)
1993
关键词indication molybdenum vanadium Fe_e H_2O MoO NO valence remarkable challenge indication molybdenum vanadium Fe_e H_2O MoO NO valence remarkable challenge
英文摘要Understanding the driving force for the formation of high nuclearity clusters is still a formidable challenge.We recently reported the structure with the largest polymetallate cluster involving mixed valence molybdenum and vanadium(Ⅳ) or iron(Ⅲ)(Zhang,Huang,Shao & Tang,J.Chem.Soc.,Chem.Commun.,(1993),1,37).Here is another remarkable cluster structure with mixed valence molybdenum and iron(Ⅱ).They may give an indication about the possible mechanism of formation of the polymolybdate.; Understanding the driving force for the formation of high nuclearity clusters is still a formidable challenge.We recently reported the structure with the largest polymetallate cluster involving mixed valence molybdenum and vanadium(Ⅳ) or iron(Ⅲ)(Zhang,Huang,Shao & Tang,J.Chem.Soc.,Chem.Commun.,(1993),1,37).Here is another remarkable cluster structure with mixed valence molybdenum and iron(Ⅱ).They may give an indication about the possible mechanism of formation of the polymolybdate.; IUCR; 1
语种英语
内容类型其他
源URL[http://ir.pku.edu.cn/handle/20.500.11897/479394]  
专题化学与分子工程学院
推荐引用方式
GB/T 7714
. CRYSTAL STRUCTURE OF A REMARKABLE POLYMETALLATE OXYGEN CLUSTER[H_6Mo_(57)Fe_e~Ⅱ(NO)_(185)(H_2O)_(16)(MoO)_2]~(6-), CRYSTAL STRUCTURE OF A REMARKABLE POLYMETALLATE OXYGEN CLUSTER[H_6Mo_(57)Fe_e~Ⅱ(NO)_(185)(H_2O)_(16)(MoO)_2]~(6-). 1993-01-01.
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