Rh(I)-Catalyzed Arylation of alpha-Diazo Phosphonates with Aryl Boronic Acids: Synthesis of Diarylmethylphosphonates | |
Zhou, Yujing ; Zhang, Yan ; Wang, Jianbo | |
刊名 | CHINESE JOURNAL OF CHEMISTRY
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2017 | |
关键词 | Rh(I)-catalysis metal carbene migratory insertion alpha-diazo phosphonates aryl boronic acids CROSS-COUPLING REACTIONS N-TOSYLHYDRAZONES CATALYZED REACTIONS ARYLBORONIC ACIDS BOND FORMATION METAL CARBENE DIAZOESTERS REAGENTS PROGRESS |
DOI | 10.1002/cjoc.201600487 |
英文摘要 | An efficient synthetic method for diarylmethylphosphonates is presented. A series of phosphonate derivatives with diverse functional groups can be accessed via a rhodium catalyzed cross-coupling reaction between a-diazo phosphonates and aryl boronic acids. Migratory insertion of rhodium carbene intermediates is postulated to be the critical step in this transformation.; National Basic Research Program of China (973 Program) [2015CB856600]; National Natural Science Foundation of China [21472004, 21332002]; SCI(E); 中国科学引文数据库(CSCD); ARTICLE; 5,SI; 621-627; 35 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/476894] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Zhou, Yujing,Zhang, Yan,Wang, Jianbo. Rh(I)-Catalyzed Arylation of alpha-Diazo Phosphonates with Aryl Boronic Acids: Synthesis of Diarylmethylphosphonates[J]. CHINESE JOURNAL OF CHEMISTRY,2017. |
APA | Zhou, Yujing,Zhang, Yan,&Wang, Jianbo.(2017).Rh(I)-Catalyzed Arylation of alpha-Diazo Phosphonates with Aryl Boronic Acids: Synthesis of Diarylmethylphosphonates.CHINESE JOURNAL OF CHEMISTRY. |
MLA | Zhou, Yujing,et al."Rh(I)-Catalyzed Arylation of alpha-Diazo Phosphonates with Aryl Boronic Acids: Synthesis of Diarylmethylphosphonates".CHINESE JOURNAL OF CHEMISTRY (2017). |
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