Palladium-Catalyzed Synthesis of Indoles and Isoquinolines with in Situ Generated Phosphinimine | |
Zhou, Qi ; Zhang, Zhikun ; Zhou, Yujing ; Li, Shichao ; Zhang, Yan ; Wang, Jianbo | |
刊名 | JOURNAL OF ORGANIC CHEMISTRY
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2017 | |
关键词 | CARBENE MIGRATORY INSERTION ALPHA-DIAZOCARBONYL COMPOUNDS H BOND FUNCTIONALIZATION MEDIATED ELECTROPHILIC CYCLIZATION OXO GOLD CARBENES ENE-YNE-KETONES C-H DIAZO-COMPOUNDS INTERNAL ALKYNES METAL CARBENE |
DOI | 10.1021/acsjoc.6b01864 |
英文摘要 | A palladium-catalyzed synthesis of polysubstituted indoles and isoquinolines through the coupling of aryl bromides with 2-alkynyl arylazides or 2-alkynyl benzylazides has been developed. This method provides straightforward access to indoles and isoquinolines with high efficiency and excellent functional group compatibility. In this transformation, the iminophosphorane in situ generated from azides is served as the nucleophile that attacks the alkyne moiety in the cyclization process.; National Basic Research Program of China (973 Program) [2015CB856600]; NSFC [21472004, 21332002]; National Key Technologies R&D Program of China [2015BAK45B01]; SCI(E); ARTICLE; 1; 48-56; 82 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/475755] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Zhou, Qi,Zhang, Zhikun,Zhou, Yujing,et al. Palladium-Catalyzed Synthesis of Indoles and Isoquinolines with in Situ Generated Phosphinimine[J]. JOURNAL OF ORGANIC CHEMISTRY,2017. |
APA | Zhou, Qi,Zhang, Zhikun,Zhou, Yujing,Li, Shichao,Zhang, Yan,&Wang, Jianbo.(2017).Palladium-Catalyzed Synthesis of Indoles and Isoquinolines with in Situ Generated Phosphinimine.JOURNAL OF ORGANIC CHEMISTRY. |
MLA | Zhou, Qi,et al."Palladium-Catalyzed Synthesis of Indoles and Isoquinolines with in Situ Generated Phosphinimine".JOURNAL OF ORGANIC CHEMISTRY (2017). |
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