One-step synthesis of hollow UO2 nanospheres via radiolytic reduction of ammonium uranyl tricarbonate | |
Wang, Yong-Ming ; Chen, Qing-De ; Shen, Xing-Hai | |
刊名 | CHINESE CHEMICAL LETTERS |
2017 | |
关键词 | Uranium dioxide Hollow nanospheres Ammonium uranyl tricarbonate (AUC) Hydrated electron (e(aq)-) gamma-Irradiation URANIUM OXIDE NANOPARTICLES IN-SITU NANOCRYSTALS CATALYSTS MICROSPHERES TEMPERATURE PERFORMANCE NANOTUBES GROWTH |
DOI | 10.1016/j.cclet.2016.06.035 |
英文摘要 | Black precipitates were successfully obtained by radiolytic reduction of ammonium uranyl tricarbonate in the aqueous solution of HCOONH4 by one step. TEM, SAED, EDS, and XRD analysis indicated that the precipitates consist of hollow UO2 nanospheres (Phi: 30-50 nm, wall thickness: 8-15 nm, and cavity diameter: 10-20 nm). The effect of HCOONH4 concentration, irradiation time and dose rate on the morphology, and size of nanospheres was investigated. Then, a gas-bubble template mechanism was proposed. (C) 2016 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier By. All rights reserved.; National Natural Science Foundation of China [91226112]; specialized research fund for the Doctored Program of Higher Education of China [20110001120121]; SCI(E); ARTICLE; 2; 197-200; 28 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/475411] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Wang, Yong-Ming,Chen, Qing-De,Shen, Xing-Hai. One-step synthesis of hollow UO2 nanospheres via radiolytic reduction of ammonium uranyl tricarbonate[J]. CHINESE CHEMICAL LETTERS,2017. |
APA | Wang, Yong-Ming,Chen, Qing-De,&Shen, Xing-Hai.(2017).One-step synthesis of hollow UO2 nanospheres via radiolytic reduction of ammonium uranyl tricarbonate.CHINESE CHEMICAL LETTERS. |
MLA | Wang, Yong-Ming,et al."One-step synthesis of hollow UO2 nanospheres via radiolytic reduction of ammonium uranyl tricarbonate".CHINESE CHEMICAL LETTERS (2017). |
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