Distal-Bond-Selective C-C Activation of Ring-Fused Cyclopentanones: An Efficient Access to Spiroindanones | |
Xia, Ying ; Wang, Jianbo ; Dong, Guangbin | |
刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
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2017 | |
关键词 | C-C activation cyclopentanones homogeneous catalysis rhodium spirocycles CARBON-CARBON BONDS METAL-CATALYZED CYCLOADDITIONS ORGANIC-SYNTHESIS SINGLE BOND INDANONES CYCLOBUTANONES CLEAVAGE ALKYNES BENZOCYCLOBUTENONES CYCLOBUTENONES |
DOI | 10.1002/anie.201611642 |
英文摘要 | A site-selective rhodium-catalyzed C-C activation of ring-fused cyclopentanones was achieved to afford efficient access to a range of spiroindanones. The use of bulky 2-amino-6-picoline as a cocatalyst is key to the excellent selectivity of this C-C bond cleavage in cyclopentanones.; NIGMS [R01GM109054]; Office of China Postdoctoral Council (OCPC) [38]; SCI(E); ARTICLE; 9; 2376-2380; 56 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/475089] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Xia, Ying,Wang, Jianbo,Dong, Guangbin. Distal-Bond-Selective C-C Activation of Ring-Fused Cyclopentanones: An Efficient Access to Spiroindanones[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017. |
APA | Xia, Ying,Wang, Jianbo,&Dong, Guangbin.(2017).Distal-Bond-Selective C-C Activation of Ring-Fused Cyclopentanones: An Efficient Access to Spiroindanones.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. |
MLA | Xia, Ying,et al."Distal-Bond-Selective C-C Activation of Ring-Fused Cyclopentanones: An Efficient Access to Spiroindanones".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017). |
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