Distal-Bond-Selective C-C Activation of Ring-Fused Cyclopentanones: An   Efficient Access to Spiroindanones

doi:10.1002/anie.201611642

CORC > 北京大学 > 化学与分子工程学院

	Distal-Bond-Selective C-C Activation of Ring-Fused Cyclopentanones: An Efficient Access to Spiroindanones
	Xia, Ying ; Wang, Jianbo ; Dong, Guangbin
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2017
关键词	C-C activation cyclopentanones homogeneous catalysis rhodium spirocycles CARBON-CARBON BONDS METAL-CATALYZED CYCLOADDITIONS ORGANIC-SYNTHESIS SINGLE BOND INDANONES CYCLOBUTANONES CLEAVAGE ALKYNES BENZOCYCLOBUTENONES CYCLOBUTENONES
DOI	10.1002/anie.201611642
英文摘要	A site-selective rhodium-catalyzed C-C activation of ring-fused cyclopentanones was achieved to afford efficient access to a range of spiroindanones. The use of bulky 2-amino-6-picoline as a cocatalyst is key to the excellent selectivity of this C-C bond cleavage in cyclopentanones.; NIGMS [R01GM109054]; Office of China Postdoctoral Council (OCPC) [38]; SCI(E); ARTICLE; 9; 2376-2380; 56
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/475089]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Xia, Ying,Wang, Jianbo,Dong, Guangbin. Distal-Bond-Selective C-C Activation of Ring-Fused Cyclopentanones: An Efficient Access to Spiroindanones[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017.
APA	Xia, Ying,Wang, Jianbo,&Dong, Guangbin.(2017).Distal-Bond-Selective C-C Activation of Ring-Fused Cyclopentanones: An Efficient Access to Spiroindanones.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION.
MLA	Xia, Ying,et al."Distal-Bond-Selective C-C Activation of Ring-Fused Cyclopentanones: An Efficient Access to Spiroindanones".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017).