Magnetic and HFEPR Studies of Exchange Coupling in a Series of it mu-Cl   Dicobalt Complexes

doi:10.1021/acs.inorgchem.6b02368

CORC > 北京大学 > 化学与分子工程学院

	Magnetic and HFEPR Studies of Exchange Coupling in a Series of it mu-Cl Dicobalt Complexes
	Liu, Jia-Jia ; Jiang, Shang-Da ; Neugebauer, Petr ; van Slageren, Joris ; Lan, Yanhua ; Wernsdorfer, Wolfgang ; Wang, Bing-Wu ; Gao, Song
刊名	INORGANIC CHEMISTRY
	2017
关键词	SINGLE-MOLECULE MAGNET ELECTRON-PARAMAGNETIC-RESONANCE TRANSITION-METAL-COMPLEXES COBALT(II) COMPLEXES WEAK FERROMAGNETISM BRIDGE ANGLE ANISOTROPY LIGAND CHAIN DIMER
DOI	10.1021/acs.inorgchem.6b02368
英文摘要	We report three dinuclear cobalt(II) complexes, [Co(L)Cl-2](2) (L = bpy, mbpy, and dmpbt), that are bridged solely by chloride ions. High-field electron paramagnetic resonance and magnetometric measurements were applied to investigate the magnetic intramolecular Co-Co interactions. Simulation results based on the multispin model reveal that the complexes are weakly ferromagnetically coupled and that the isotropic exchange coupling constants differ slightly for the three complexes. Moreover, the competing effects of zero-field splitting and magnetic coupling on the temperature-dependent magnetic susceptibility were analyzed.; NSFC [21171010, 91422302, 21321001, 21290170, 21290171]; National Basic Research Program of China [2013CB933401]; Young Elite Scientist Sponsorship Program of the China Association of Science and Technology [2015QNRC001]; EU [610449]; Agence Nationale de la Recherche for project MolQuSpin [ANR-13-BS10]; DFG [SPP1601, INST41/863, NE1900/2-1]; SCI(E); ARTICLE; 5; 2417-2425; 56
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/474667]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Liu, Jia-Jia,Jiang, Shang-Da,Neugebauer, Petr,et al. Magnetic and HFEPR Studies of Exchange Coupling in a Series of it mu-Cl Dicobalt Complexes[J]. INORGANIC CHEMISTRY,2017.
APA	Liu, Jia-Jia.,Jiang, Shang-Da.,Neugebauer, Petr.,van Slageren, Joris.,Lan, Yanhua.,...&Gao, Song.(2017).Magnetic and HFEPR Studies of Exchange Coupling in a Series of it mu-Cl Dicobalt Complexes.INORGANIC CHEMISTRY.
MLA	Liu, Jia-Jia,et al."Magnetic and HFEPR Studies of Exchange Coupling in a Series of it mu-Cl Dicobalt Complexes".INORGANIC CHEMISTRY (2017).