Copper(I)-Catalyzed Chemoselective Coupling of Cyclopropanols with   Diazoesters: Ring-Opening C-C Bond Formations

doi:10.1002/anie.201612138

CORC > 北京大学 > 化学与分子工程学院

	Copper(I)-Catalyzed Chemoselective Coupling of Cyclopropanols with Diazoesters: Ring-Opening C-C Bond Formations
	Zhang, Hang ; Wu, Guojiao ; Yi, Heng ; Sun, Tong ; Wang, Bo ; Zhang, Yan ; Dong, Guangbin ; Wang, Jianbo
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2017
关键词	carbenes C C coupling reactions copper diazo compounds small ring compounds O-H INSERTION ALPHA-DIAZOCARBONYL COMPOUNDS CATALYZED 3+2 CYCLOADDITION DIAZO-COMPOUNDS MOLECULAR CALCULATIONS CARBENE INSERTION GOLD CATALYSIS FUNCTIONALIZATION CHEMISTRY DENSITY
DOI	10.1002/anie.201612138
英文摘要	Reported herein is an exceptional chemoselective ring-opening/C(sp(3))@C(sp(3)) bond formation in the copper(I)-catalyzed reaction of cyclopropanols with diazo esters. The conventional O H insertion product is essentially suppressed by judicious choice of reaction conditions. DFT calculations provide insights into the reaction mechanism and the rationale for this unusual chemoselectivity.; 973 program of China [2015CB856600]; NSFC [21332002]; SCI(E); ARTICLE; 14; 3945-3950; 56
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/474486]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Zhang, Hang,Wu, Guojiao,Yi, Heng,et al. Copper(I)-Catalyzed Chemoselective Coupling of Cyclopropanols with Diazoesters: Ring-Opening C-C Bond Formations[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017.
APA	Zhang, Hang.,Wu, Guojiao.,Yi, Heng.,Sun, Tong.,Wang, Bo.,...&Wang, Jianbo.(2017).Copper(I)-Catalyzed Chemoselective Coupling of Cyclopropanols with Diazoesters: Ring-Opening C-C Bond Formations.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION.
MLA	Zhang, Hang,et al."Copper(I)-Catalyzed Chemoselective Coupling of Cyclopropanols with Diazoesters: Ring-Opening C-C Bond Formations".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017).