Aliphatic C-H azidation through a peroxydisulfate induced radical   pathway

doi:10.1039/c6qo00237d

CORC > 北京大学 > 化学与分子工程学院

	Aliphatic C-H azidation through a peroxydisulfate induced radical pathway
	Li, Xin ; Shi, Zhang-Jie
刊名	ORGANIC CHEMISTRY FRONTIERS
	2016
关键词	TRIISOPROPYLSILYL ENOL ETHERS BETA-AZIDO FUNCTIONALIZATION BOND FUNCTIONALIZATION ORGANIC AZIDES PHOTOCHEMICAL-REACTION STABLE AZIDOIODINANES TRIMETHYLSILYL AZIDE CATALYZED AZIDATION REAGENT COMBINATION NATURAL-PRODUCTS
DOI	10.1039/c6qo00237d
英文摘要	A persulfate induced radical process to transform aliphatic tertiary C-H bonds into organic azides under transition-metal-free conditions has been developed. This method exhibits good chemo- and regio-selectivity. A wide range of functional groups, including esters, halogens, azides, and dipeptides, are all tolerated well through the radical pathway, thus expanding the potential application of this method.; National Basic Research Program of China (973 Program) [2015CB856600]; National Nature Science Foundation of China [21332001]; SCI(E); ARTICLE; zshi@pku.edu.cn; 10; 1326-1330; 3
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/457548]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Li, Xin,Shi, Zhang-Jie. Aliphatic C-H azidation through a peroxydisulfate induced radical pathway[J]. ORGANIC CHEMISTRY FRONTIERS,2016.
APA	Li, Xin,&Shi, Zhang-Jie.(2016).Aliphatic C-H azidation through a peroxydisulfate induced radical pathway.ORGANIC CHEMISTRY FRONTIERS.
MLA	Li, Xin,et al."Aliphatic C-H azidation through a peroxydisulfate induced radical pathway".ORGANIC CHEMISTRY FRONTIERS (2016).