Open-cage fullerene with a stopper acts as a molecular vial for a single   water molecule

doi:10.1039/c5qo00265f

CORC > 北京大学 > 化学与分子工程学院

	Open-cage fullerene with a stopper acts as a molecular vial for a single water molecule
	Xu, Liang ; Liang, Sisi ; Sun, Jiahao ; Gan, Liangbing
刊名	Organic Chemistry Frontiers
	2015
关键词	HYDROGEN-FLUORIDE ENCAPSULATION C-60 DERIVATIVES CARBONYL GUESTS HOST RIM
DOI	10.1039/c5qo00265f
英文摘要	An open-cage fullerene derivative with three carbonyl groups on the rim of the orifice reacts with o-diaminobenzene reversibly to form a tetrahydrofuran moiety above the orifice. Water encapsulation and release experiments show that the tetrahydrofuran moiety acts as a stopper effectively blocking the orifice. The addition and removal of o-diaminobenzene serve as a chemically controlled switching process for the fullerene-based water container, which is suited for just one water molecule due to its moderate cavity size.; NSFC [21272013, 21132007]; Major State Basic Research Development Program [2011CB808401, 2015CB856600]; SCI(E); ARTICLE; gan@pku.edu.cn; 11; 1500-1504; 2
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/439567]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Xu, Liang,Liang, Sisi,Sun, Jiahao,et al. Open-cage fullerene with a stopper acts as a molecular vial for a single water molecule[J]. Organic Chemistry Frontiers,2015.
APA	Xu, Liang,Liang, Sisi,Sun, Jiahao,&Gan, Liangbing.(2015).Open-cage fullerene with a stopper acts as a molecular vial for a single water molecule.Organic Chemistry Frontiers.
MLA	Xu, Liang,et al."Open-cage fullerene with a stopper acts as a molecular vial for a single water molecule".Organic Chemistry Frontiers (2015).