Cu(I)-catalyzed coupling of diaryldiazomethanes with terminal alkynes:   an efficient synthesis of tri-aryl-substituted allenes

doi:10.1016/j.tet.2015.10.043

CORC > 北京大学 > 化学与分子工程学院

	Cu(I)-catalyzed coupling of diaryldiazomethanes with terminal alkynes: an efficient synthesis of tri-aryl-substituted allenes
	Wu, Chenggui ; Hu, Fangdong ; Liu, Zhenxing ; Deng, Guisheng ; Ye, Fei ; Zhang, Yan ; Wang, Jianbo
刊名	TETRAHEDRON
	2015
关键词	Cross-coupling Diazo compounds Allene Terminal alkyne Synthesis ONE-POT SYNTHESIS N-TOSYLHYDRAZONES 1,3-DISUBSTITUTED ALLENES CATALYZED SYNTHESIS ALPHA-DIAZOESTERS DIAZO-COMPOUNDS ALLENOATES CHEMISTRY INSERTION
DOI	10.1016/j.tet.2015.10.043
英文摘要	A highly efficient method for the synthesis of tri-aryl-substituted allenes has been developed through Cu(I)-catalyzed coupling of diaryldiazomethanes with terminal alkynes. The reaction is under mild conditions and uses simple and inexpensive CuI as the catalyst. Mechanistically, the reaction follows a pathway involving Cu(I) carbene migratory insertion. (C) 2015 Elsevier Ltd. All rights reserved.; National Basic Research Program (973 Program) [2012CB821600]; National Natural Science Foundation of China [21272010, 21332002]; SCI(E); ARTICLE; wangjb@pku.edu.cn; 49; 9196-9201; 71
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/439076]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Wu, Chenggui,Hu, Fangdong,Liu, Zhenxing,et al. Cu(I)-catalyzed coupling of diaryldiazomethanes with terminal alkynes: an efficient synthesis of tri-aryl-substituted allenes[J]. TETRAHEDRON,2015.
APA	Wu, Chenggui.,Hu, Fangdong.,Liu, Zhenxing.,Deng, Guisheng.,Ye, Fei.,...&Wang, Jianbo.(2015).Cu(I)-catalyzed coupling of diaryldiazomethanes with terminal alkynes: an efficient synthesis of tri-aryl-substituted allenes.TETRAHEDRON.
MLA	Wu, Chenggui,et al."Cu(I)-catalyzed coupling of diaryldiazomethanes with terminal alkynes: an efficient synthesis of tri-aryl-substituted allenes".TETRAHEDRON (2015).