Preparation of Azafullerene C59NR5 and Fullerene Derivative C60NAr5 with   a Pyridine Moiety on the Cage Skeleton

doi:10.1021/acs.orglett.6b00872

CORC > 北京大学 > 化学与分子工程学院

	Preparation of Azafullerene C59NR5 and Fullerene Derivative C60NAr5 with a Pyridine Moiety on the Cage Skeleton
	Lou, Ning ; Li, Yanbang ; Cui, Chengxing ; Liu, Yajun ; Gan, Liangbing
刊名	ORGANIC LETTERS
	2016
关键词	ELECTROPHILIC AROMATIC-SUBSTITUTION ORGANIC SOLAR-CELLS CHEMICAL-SYNTHESIS C-60 NITROGEN HETEROFULLERENES PENTAARYLAZAFULLERENES PRECURSORS ACCEPTORS C60CL6
DOI	10.1021/acs.orglett.6b00872
英文摘要	[60]Fullerene hexaadducts C60R5Cl (R = OMe or Ar) reacted with hydroxylamine to form C60R5(NHOH) with the hydroxylamino group attached on the central pentagon as in the starting material. Further reactions including treatment with PCl5 and basic alumina led to the insertion of the nitrogen atom into the fullerene cage skeleton and decarbonylation to form azafullerenes C59N(H)(OMe)(4) and C59N(OMe)(5). The fullerene derivatives C59N(CO)R-5 and C60NAr5 with a pyridinone and a pyridine moiety on the cage skeleton, respectively, were also synthesized starting from the hydroxylamine adducts.; NNSFC [21272013, 21132007]; MOST [2015CB856600]; SCI(E); ARTICLE; yajun.liu@bnu.edu.cn; gan@pku.edu.cn; 9; 2236-2239; 18
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/438193]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Lou, Ning,Li, Yanbang,Cui, Chengxing,et al. Preparation of Azafullerene C59NR5 and Fullerene Derivative C60NAr5 with a Pyridine Moiety on the Cage Skeleton[J]. ORGANIC LETTERS,2016.
APA	Lou, Ning,Li, Yanbang,Cui, Chengxing,Liu, Yajun,&Gan, Liangbing.(2016).Preparation of Azafullerene C59NR5 and Fullerene Derivative C60NAr5 with a Pyridine Moiety on the Cage Skeleton.ORGANIC LETTERS.
MLA	Lou, Ning,et al."Preparation of Azafullerene C59NR5 and Fullerene Derivative C60NAr5 with a Pyridine Moiety on the Cage Skeleton".ORGANIC LETTERS (2016).