Self-Supporting Metal-Organic Layers as Single-Site Solid Catalysts

doi:10.1002/anie.201512054

CORC > 北京大学 > 化学与分子工程学院

	Self-Supporting Metal-Organic Layers as Single-Site Solid Catalysts
	Cao, Lingyun ; Lin, Zekai ; Peng, Fei ; Wang, Weiwei ; Huang, Ruiyun ; Wang, Cheng ; Yan, Jiawei ; Liang, Jie ; Zhang, Zhiming ; Zhang, Teng ; Long, Lasheng ; Sun, Junliang ; Lin, Wenbin
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2016
关键词	alkenes hafnium heterogeneous catalysis hydrosilylation metal-organic layers FRAMEWORK NANOSHEETS ROOM-TEMPERATURE 2D EPOXIDATION STABILITY EVOLUTION SHEETS FILMS
DOI	10.1002/anie.201512054
英文摘要	Metal-organic layers (MOLs) represent an emerging class of tunable and functionalizable two-dimensional materials. In this work, the scalable solvothermal synthesis of self-supporting MOLs composed of [Hf6O4(OH)(4)(HCO2)(6)] secondary building units (SBUs) and benzene-1,3,5-tribenzoate (BTB) bridging ligands is reported. The MOL structures were directly imaged by TEM and AFM, and doped with 4-(4-benzoate)-(2,2,2-terpyridine)-5,5-dicarboxylate (TPY) before being coordinated with iron centers to afford highly active and reusable single-site solid catalysts for the hydrosilylation of terminal olefins. MOL-based heterogeneous catalysts are free from the diffusional constraints placed on all known porous solid catalysts, including metal-organic frameworks. This work uncovers an entirely new strategy for designing single-site solid catalysts and opens the door to a new class of two-dimensional coordination materials with molecular functionalities.; National Natural Science Foundation of P.R. China [21471126]; National Thousand Talents Program of P.R. China; 985 Program of Chemistry and Chemical Engineering disciplines of Xiamen University; US National Science Foundation [CHE-1464941]; Chicago MRSEC - NSF [DMR-1420709]; National Science Foundation [NSF/CHE-1346572]; U.S. DOE [DE-AC02-06CH11357]; SCI(E); EI; ARTICLE; wangchengxmu@xmu.edu.cn; junliang.sun@pku.edu.cn; wenbinlin@uchicago.edu; 16; 4962-4966; 55
语种	中文
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/437411]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Cao, Lingyun,Lin, Zekai,Peng, Fei,et al. Self-Supporting Metal-Organic Layers as Single-Site Solid Catalysts[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016.
APA	Cao, Lingyun.,Lin, Zekai.,Peng, Fei.,Wang, Weiwei.,Huang, Ruiyun.,...&Lin, Wenbin.(2016).Self-Supporting Metal-Organic Layers as Single-Site Solid Catalysts.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION.
MLA	Cao, Lingyun,et al."Self-Supporting Metal-Organic Layers as Single-Site Solid Catalysts".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016).