Silver-Catalyzed Long-Distance Aryl Migration from Carbon Center to   Nitrogen Center

doi:10.1021/jacs.5b10267

CORC > 北京大学 > 化学与分子工程学院

	Silver-Catalyzed Long-Distance Aryl Migration from Carbon Center to Nitrogen Center
	Zhou, Taigang ; Luo, Fei-Xian ; Yang, Ming-Yu ; Shi, Zhang-Jie
刊名	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
	2015
关键词	BOND-CLEAVAGE REACTIONS ARYLCYCLOPROPANE CATION RADICALS 3-ELECTRON S(N)2 REACTIONS O-NEOPHYL REARRANGEMENT C-C BONDS 1,1-DIARYLALKOXYL RADICALS DEAROMATIZATION REACTIONS UNACTIVATED ALKENES ALLYLIC ALCOHOLS DOMINO REACTION
DOI	10.1021/jacs.5b10267
英文摘要	Selective cleavage of an inert C-C bond followed by C-O/N bond formation through a long-distance aryl migration from a carbon to a nitrogen center via Ag catalysis is reported. The migration products were easily converted into gamma-hydroxy amines and tetrahydroquinoline derivatives in quantitative yields. Preliminary mechanistic studies indicated a radical pathway.; MOST [2015CB856600]; NSFC [21332001, 21431008]; Peking-Tsinghua Center for Life Sciences; China Postdoctoral Science Foundation [2014 M550546]; SCI(E); EI; ARTICLE; zshi@pku.edu.cn; 46; 14586-14589; 137
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/435780]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Zhou, Taigang,Luo, Fei-Xian,Yang, Ming-Yu,et al. Silver-Catalyzed Long-Distance Aryl Migration from Carbon Center to Nitrogen Center[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2015.
APA	Zhou, Taigang,Luo, Fei-Xian,Yang, Ming-Yu,&Shi, Zhang-Jie.(2015).Silver-Catalyzed Long-Distance Aryl Migration from Carbon Center to Nitrogen Center.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY.
MLA	Zhou, Taigang,et al."Silver-Catalyzed Long-Distance Aryl Migration from Carbon Center to Nitrogen Center".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015).