Silver-Catalyzed Long-Distance Aryl Migration from Carbon Center to Nitrogen Center | |
Zhou, Taigang ; Luo, Fei-Xian ; Yang, Ming-Yu ; Shi, Zhang-Jie | |
刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
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2015 | |
关键词 | BOND-CLEAVAGE REACTIONS ARYLCYCLOPROPANE CATION RADICALS 3-ELECTRON S(N)2 REACTIONS O-NEOPHYL REARRANGEMENT C-C BONDS 1,1-DIARYLALKOXYL RADICALS DEAROMATIZATION REACTIONS UNACTIVATED ALKENES ALLYLIC ALCOHOLS DOMINO REACTION |
DOI | 10.1021/jacs.5b10267 |
英文摘要 | Selective cleavage of an inert C-C bond followed by C-O/N bond formation through a long-distance aryl migration from a carbon to a nitrogen center via Ag catalysis is reported. The migration products were easily converted into gamma-hydroxy amines and tetrahydroquinoline derivatives in quantitative yields. Preliminary mechanistic studies indicated a radical pathway.; MOST [2015CB856600]; NSFC [21332001, 21431008]; Peking-Tsinghua Center for Life Sciences; China Postdoctoral Science Foundation [2014 M550546]; SCI(E); EI; ARTICLE; zshi@pku.edu.cn; 46; 14586-14589; 137 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/435780] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Zhou, Taigang,Luo, Fei-Xian,Yang, Ming-Yu,et al. Silver-Catalyzed Long-Distance Aryl Migration from Carbon Center to Nitrogen Center[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2015. |
APA | Zhou, Taigang,Luo, Fei-Xian,Yang, Ming-Yu,&Shi, Zhang-Jie.(2015).Silver-Catalyzed Long-Distance Aryl Migration from Carbon Center to Nitrogen Center.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. |
MLA | Zhou, Taigang,et al."Silver-Catalyzed Long-Distance Aryl Migration from Carbon Center to Nitrogen Center".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015). |
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