Visible-Light-Promoted Generation of Hydrogen from the Hydrolysis of   Silanes Catalyzed by Rhodium(III) Porphyrins

doi:10.1021/acs.organomet.5b00521

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	Visible-Light-Promoted Generation of Hydrogen from the Hydrolysis of Silanes Catalyzed by Rhodium(III) Porphyrins
	Yu, Mengmeng ; Jing, Huize ; Liu, Xu ; Fu, Xuefeng
刊名	ORGANOMETALLICS
	2015
关键词	H BOND ACTIVATION EQUILIBRIUM THERMODYNAMICS ORGANOMETALLIC REACTIONS SUBSTRATE REACTIONS FACILE SYNTHESIS RH-OH COMPLEXES OXIDATION WATER ORGANOSILANES
DOI	10.1021/acs.organomet.5b00521
英文摘要	Visible-light-promoted hydrolysis of silanes catalyzed by (TAP)Rh-I to produce silanols and dihydrogen efficiently under mild conditions was reported. (TAP)Rh-H was observed as the key intermediate through stoichiometric activation of the Si-H bond by (TAP)Rh-I. Addition of water drove the stoichiometric activation of Si-H into catalysis.; Nature Science Foundation of China [21322108, 21321001]; SCI(E); EI; ARTICLE; fuxf@pku.edu.cn; 24; 5754-5758; 34
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/435519]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Yu, Mengmeng,Jing, Huize,Liu, Xu,et al. Visible-Light-Promoted Generation of Hydrogen from the Hydrolysis of Silanes Catalyzed by Rhodium(III) Porphyrins[J]. ORGANOMETALLICS,2015.
APA	Yu, Mengmeng,Jing, Huize,Liu, Xu,&Fu, Xuefeng.(2015).Visible-Light-Promoted Generation of Hydrogen from the Hydrolysis of Silanes Catalyzed by Rhodium(III) Porphyrins.ORGANOMETALLICS.
MLA	Yu, Mengmeng,et al."Visible-Light-Promoted Generation of Hydrogen from the Hydrolysis of Silanes Catalyzed by Rhodium(III) Porphyrins".ORGANOMETALLICS (2015).