Pd(0)-catalyzed cross-coupling of allyl halides with alpha-diazocarbonyl   compounds or N-mesylhydrazones: synthesis of 1,3-diene compounds

doi:10.1039/c6ob00454g

CORC > 北京大学 > 化学与分子工程学院

	Pd(0)-catalyzed cross-coupling of allyl halides with alpha-diazocarbonyl compounds or N-mesylhydrazones: synthesis of 1,3-diene compounds
	Wang, Kang ; Chen, Shufeng ; Zhang, Hang ; Xu, Shuai ; Ye, Fei ; Zhang, Yan ; Wang, Jianbo
刊名	ORGANIC & BIOMOLECULAR CHEMISTRY
	2016
关键词	CARBENE MIGRATORY INSERTION DIELS-ALDER REACTION C BOND FORMATION DIAZO-COMPOUNDS CATALYZED REACTIONS CONJUGATED DIENES STEREOSELECTIVE-SYNTHESIS CYCLIZATION SYNTHESIS OLEFINATION REACTION SELECTIVE SYNTHESIS
DOI	10.1039/c6ob00454g
英文摘要	With palladium catalysis, allyl bromides or chlorides react with alpha-diazocarbonyl compounds or N-mesylhydrazones to afford 1,3-diene derivatives. The reaction represents a novel and efficient method for the synthesis of 1,3-butadiene derivatives. Mechanistically, the reaction is proposed to follow a pathway involving the formation of a pi-allylic palladium carbene complex and subsequent migratory insertion.; National Basic Research Program of China (973 Program) [2012CB821600]; National Natural Science Foundation of China [21472004, 21332002]; SCI(E); EI; PubMed; ARTICLE; wangjb@pku.edu.cn; 15; 3809-3820; 14
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/434308]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Wang, Kang,Chen, Shufeng,Zhang, Hang,et al. Pd(0)-catalyzed cross-coupling of allyl halides with alpha-diazocarbonyl compounds or N-mesylhydrazones: synthesis of 1,3-diene compounds[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2016.
APA	Wang, Kang.,Chen, Shufeng.,Zhang, Hang.,Xu, Shuai.,Ye, Fei.,...&Wang, Jianbo.(2016).Pd(0)-catalyzed cross-coupling of allyl halides with alpha-diazocarbonyl compounds or N-mesylhydrazones: synthesis of 1,3-diene compounds.ORGANIC & BIOMOLECULAR CHEMISTRY.
MLA	Wang, Kang,et al."Pd(0)-catalyzed cross-coupling of allyl halides with alpha-diazocarbonyl compounds or N-mesylhydrazones: synthesis of 1,3-diene compounds".ORGANIC & BIOMOLECULAR CHEMISTRY (2016).