Structural Distortion Controlled Spin-Crossover Behavior

doi:10.1021/acs.cgd.5b00175

CORC > 北京大学 > 化学与分子工程学院

	Structural Distortion Controlled Spin-Crossover Behavior
	Yang, Qian ; Cheng, Xin ; Gao, Chen ; Wang, BingWu ; Wang, ZheMing ; Gao, Song
刊名	CRYSTAL GROWTH & DESIGN
	2015
关键词	ROOM-TEMPERATURE TRANSITION COMPLEXES PRESSURE HYSTERESIS DEVICES SERIES LIGHT
DOI	10.1021/acs.cgd.5b00175
英文摘要	Two mononuclear isomorphous complexes Fe(L1)(2)(SCN)(2) (1) and Fe(L2)(2)(SCN)(2) (2) [L1 = 2-(pyridin-3-yl)-1H-imidazo[4,5-f]1,10-phenanthroline; L2 = 2-(pyridin-4-yl)-1H-imidazo [4,5-f]1,10-phenanthroline] were obtained based on 1,10-plienanthroline derivatives. Due to the different structural distortion in the coordination geometries, 1 exhibits gradual spin transition around room temperature (T-1/2 = 315 K), while 2 displays a stable high-spin state.; Natural Science Foundation of China [21290171, 21321001]; National Basic Research Program [2013CB933401]; China Postdoctoral Science Foundation [2013M530469]; SCI(E); EI; ARTICLE; wangbw@pku.edu.cn; gaosong@pku.edu.cn; 6; 2565-2567; 15
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/419690]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Yang, Qian,Cheng, Xin,Gao, Chen,et al. Structural Distortion Controlled Spin-Crossover Behavior[J]. CRYSTAL GROWTH & DESIGN,2015.
APA	Yang, Qian,Cheng, Xin,Gao, Chen,Wang, BingWu,Wang, ZheMing,&Gao, Song.(2015).Structural Distortion Controlled Spin-Crossover Behavior.CRYSTAL GROWTH & DESIGN.
MLA	Yang, Qian,et al."Structural Distortion Controlled Spin-Crossover Behavior".CRYSTAL GROWTH & DESIGN (2015).