Hydrogen-Bonding-Induced Nanophase Separation in Giant Surfactants   Consisting of Hydrophilic [60]Fullerene Tethered to Block Copolymers at   Different Locations

doi:10.1021/acs.macromol.5b00741

CORC > 北京大学 > 化学与分子工程学院

	Hydrogen-Bonding-Induced Nanophase Separation in Giant Surfactants Consisting of Hydrophilic [60]Fullerene Tethered to Block Copolymers at Different Locations
	Lin, Zhiwei ; Lu, Pengtao ; Hsu, Chih-Hao ; Sun, Jian ; Zhou, Yangbin ; Huang, Mingjun ; Yue, Kan ; Ni, Bo ; Dong, Xue-Hui ; Li, Xiaochen ; Zhang, Wen-Bin ; Yu, Xinfei ; Cheng, Stephen Z. D.
刊名	MACROMOLECULES
	2015
关键词	POLYHEDRAL OLIGOMERIC SILSESQUIOXANE ORDERED HYBRID MATERIALS DIBLOCK-COPOLYMER SHAPE AMPHIPHILES GOLD NANOPARTICLES SELF-ORGANIZATION MOLECULAR NANOPARTICLES PRECISE SYNTHESIS PHASE-SEPARATION CLICK SYNTHESIS
DOI	10.1021/acs.macromol.5b00741
英文摘要	Phase behaviors of two series of giant surfactants consisting of a hydrophilic [60]fullerene (AC(60)) molecular nanoparticle (MNP) tethered to a polystyrene-block-poly(ethylene oxide) (PS-b-PEO) block copolymer were investigated. The physical location of AC(60) MNP was specifically designed to be at the end of the PS block (AC(60)-PS-PEO) or at the junction point [PS-(AC(60))-PEO] between the PS and PEO blocks. Sell-assemblies of these two series of giant surfactants in the bulk revealed that the incorporation of AC(60) MNPs leads to nanophase separation of originally disordered PS-b-PEO block copolymers having their block lengths shorter than the limiting value for the nanophase separation in the PS-b-PEO precursors. Based on small-angle X-ray scattering and transmission electron microscopy results, three ordered nanostructures were observed in these two series of giant surfactants, including lamellae, double gyroids, and cylinders, all of which possess domain sizes smaller than 10 nm. Two pairs of topological isomers, AC(60)-PS50-PEO45 and PS50-(AC(60))-PEO45 as well as AC(60)-PS78-PEO45 and PS78-(AC(60))-PEO45, were explicitly investigated to reveal the topological effect on self-assembly behaviors of these giant surfactants. The results provided evidence of the physical location and distribution of the AC(60) MNPs within the nanophase-separated domains and demonstrated abilities to stabilize the different structures via topological variations. This study thus affords an efficient and practical strategy for the design and preparation of giant surfactants to construct ordered nanostructures for technologically relevant applications.; National Science Foundation [DMR-1408872]; SCI(E); EI; ARTICLE; wenbin@pku.edu.cn; xy5@zips.uakron.edu; scheng@uakron.edu; 16; 5496-5503; 48
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/417092]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Lin, Zhiwei,Lu, Pengtao,Hsu, Chih-Hao,et al. Hydrogen-Bonding-Induced Nanophase Separation in Giant Surfactants Consisting of Hydrophilic [60]Fullerene Tethered to Block Copolymers at Different Locations[J]. MACROMOLECULES,2015.
APA	Lin, Zhiwei.,Lu, Pengtao.,Hsu, Chih-Hao.,Sun, Jian.,Zhou, Yangbin.,...&Cheng, Stephen Z. D..(2015).Hydrogen-Bonding-Induced Nanophase Separation in Giant Surfactants Consisting of Hydrophilic [60]Fullerene Tethered to Block Copolymers at Different Locations.MACROMOLECULES.
MLA	Lin, Zhiwei,et al."Hydrogen-Bonding-Induced Nanophase Separation in Giant Surfactants Consisting of Hydrophilic [60]Fullerene Tethered to Block Copolymers at Different Locations".MACROMOLECULES (2015).