Diversity-Oriented Synthesis through Rh-Catalyzed Selective   Transformations of a Novel Multirole Directing Group

doi:10.1002/cctc.201500410

CORC > 北京大学 > 化学与分子工程学院

	Diversity-Oriented Synthesis through Rh-Catalyzed Selective Transformations of a Novel Multirole Directing Group
	Su, Bo ; Wei, Jiang-bo ; Wu, Wen-lian ; Shi, Zhang-jie
刊名	CHEMCATCHEM
	2015
关键词	alkynes CH activation directing groups redox chemistry rhodium C-H ACTIVATION BOND ACTIVATION REGIOSELECTIVE SYNTHESIS INTERNAL ALKYNES INDOLE SYNTHESIS ISOQUINOLONE SYNTHESIS EFFICIENT SYNTHESIS ORGANIC-SYNTHESIS OXIME ESTERS O BOND
DOI	10.1002/cctc.201500410
英文摘要	In the context of transition-metal-catalyzed CH functionalization, directing-group strategy was developed for the improvement of chemical reactivity and selectivity. Recently, to avoid the inherent limitations of traditional mono-role directing groups, a dual-role oxidizing-directing-group strategy was developed, in which the directing group acts both as directing group and oxidant. Herein, we report a multirole directing group, which possesses multiple reactive sites, exhibits unique reactivity and selectivity, and leads to four different types of products from a single starting material through rhodium-catalyzed CH activation/alkyne annulation reactions. The excellent product diversity and regio- and redox selectivity were well controlled by the tuning of solvents and oxidants.; "973" Project from the MOST of China [2013CB228102, 2015CB856600]; NSFC [21332001, 21431008]; MSD China Postdoctoral Research Fellow Program; SCI(E); ARTICLE; zshi@pku.edu.cn; 18,SI; 2986-2990; 7
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/416298]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Su, Bo,Wei, Jiang-bo,Wu, Wen-lian,et al. Diversity-Oriented Synthesis through Rh-Catalyzed Selective Transformations of a Novel Multirole Directing Group[J]. CHEMCATCHEM,2015.
APA	Su, Bo,Wei, Jiang-bo,Wu, Wen-lian,&Shi, Zhang-jie.(2015).Diversity-Oriented Synthesis through Rh-Catalyzed Selective Transformations of a Novel Multirole Directing Group.CHEMCATCHEM.
MLA	Su, Bo,et al."Diversity-Oriented Synthesis through Rh-Catalyzed Selective Transformations of a Novel Multirole Directing Group".CHEMCATCHEM (2015).