Well-Defined Butadienyl Organocopper(I) Aggregates from   Zirconacyclopentadienes and CuCl: Synthesis and Structural   Characterization

doi:10.1021/acs.organomet.5b00598

CORC > 北京大学 > 化学与分子工程学院

	Well-Defined Butadienyl Organocopper(I) Aggregates from Zirconacyclopentadienes and CuCl: Synthesis and Structural Characterization
	Liu, Liang ; Geng, Weizhi ; Yang, Qi ; Zhang, Wen-Xiong ; Xi, Zhenfeng
刊名	ORGANOMETALLICS
	2015
关键词	SKELETAL REARRANGEMENT CYCLOADDITION REACTION BENZENE-DERIVATIVES ALKYNES COPPER(I) COMPLEXES CHEMISTRY LIGAND ARYL 1,4-DILITHIO-1,3-DIENES
DOI	10.1021/acs.organomet.5b00598
英文摘要	Two examples of mixed alkenyl/aryl organocopper(I) aggregates possessing conjugated alkenyl/aryl C-Cu bonds were synthesized by transmetalation of zirconaindenes with CuCl. Single-crystal X-ray structural analysis revealed tetrameric and hexameric structures. Butadienyl copper(I) aggregates were also synthesized and structurally characterized for further comparison. The preliminary reaction chemistry of the copper(I) aggregates was studied.; 973 Program [2011CB808700]; Natural Science Foundation of China (NSFC); SCI(E); EI; ARTICLE; zfxi@pku.edu.cn; 17; 4198-4201; 34
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/416296]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Liu, Liang,Geng, Weizhi,Yang, Qi,et al. Well-Defined Butadienyl Organocopper(I) Aggregates from Zirconacyclopentadienes and CuCl: Synthesis and Structural Characterization[J]. ORGANOMETALLICS,2015.
APA	Liu, Liang,Geng, Weizhi,Yang, Qi,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2015).Well-Defined Butadienyl Organocopper(I) Aggregates from Zirconacyclopentadienes and CuCl: Synthesis and Structural Characterization.ORGANOMETALLICS.
MLA	Liu, Liang,et al."Well-Defined Butadienyl Organocopper(I) Aggregates from Zirconacyclopentadienes and CuCl: Synthesis and Structural Characterization".ORGANOMETALLICS (2015).