Well-Defined Butadienyl Organocopper(I) Aggregates from Zirconacyclopentadienes and CuCl: Synthesis and Structural Characterization | |
Liu, Liang ; Geng, Weizhi ; Yang, Qi ; Zhang, Wen-Xiong ; Xi, Zhenfeng | |
刊名 | ORGANOMETALLICS
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2015 | |
关键词 | SKELETAL REARRANGEMENT CYCLOADDITION REACTION BENZENE-DERIVATIVES ALKYNES COPPER(I) COMPLEXES CHEMISTRY LIGAND ARYL 1,4-DILITHIO-1,3-DIENES |
DOI | 10.1021/acs.organomet.5b00598 |
英文摘要 | Two examples of mixed alkenyl/aryl organocopper(I) aggregates possessing conjugated alkenyl/aryl C-Cu bonds were synthesized by transmetalation of zirconaindenes with CuCl. Single-crystal X-ray structural analysis revealed tetrameric and hexameric structures. Butadienyl copper(I) aggregates were also synthesized and structurally characterized for further comparison. The preliminary reaction chemistry of the copper(I) aggregates was studied.; 973 Program [2011CB808700]; Natural Science Foundation of China (NSFC); SCI(E); EI; ARTICLE; zfxi@pku.edu.cn; 17; 4198-4201; 34 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/416296] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Liu, Liang,Geng, Weizhi,Yang, Qi,et al. Well-Defined Butadienyl Organocopper(I) Aggregates from Zirconacyclopentadienes and CuCl: Synthesis and Structural Characterization[J]. ORGANOMETALLICS,2015. |
APA | Liu, Liang,Geng, Weizhi,Yang, Qi,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2015).Well-Defined Butadienyl Organocopper(I) Aggregates from Zirconacyclopentadienes and CuCl: Synthesis and Structural Characterization.ORGANOMETALLICS. |
MLA | Liu, Liang,et al."Well-Defined Butadienyl Organocopper(I) Aggregates from Zirconacyclopentadienes and CuCl: Synthesis and Structural Characterization".ORGANOMETALLICS (2015). |
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