Formation of W/O microemulsions in TBP-Pd(II)-HCl extraction system and spectroscopic research on the evolution of solution aggregation structure

CORC > 北京大学 > 化学与分子工程学院

	Formation of W/O microemulsions in TBP-Pd(II)-HCl extraction system and spectroscopic research on the evolution of solution aggregation structure
	Huang, Kun ; Qi, Jian ; Liu, Xue-Xin ; Liu, Yu-Feng ; Li, Wei-Hong ; Yang, Zhan-Lan ; Weng, Shi-Fu ; Xu, Yi-Zhuang ; Wu, Jin-Guang
刊名	guang pu xue yu guang pu fen xispectroscopy and spectral analysis
	2008
英文摘要	The formation of W/O microemulsions in the extraction system TBP-Pd(II)-HCl was investigated. The solution structural evolution of the palladium loaded organic phases, with the variation in the content of acid into the organic phases, was characterized by various spectroscopic techniques such as DLS, FTIR and 31P-/1H NMR. The results indicated that (1) the extraction behaviors of palladium was related to the formation of W/O microemulsion structure in the loaded organic solutions. Because of the co-extraction of hydrochloric acid, there formed the microscopic aggregates in the loaded organic phases. (2) The variation in the HCl content in organic phase resulted in corresponding changes in solution structure. With the increase in the HCl content, the average radii of nanoscopic aggregates in the organic phases increased and then decreased. The extraction of HCl into the organic phase exhibited a distinct impact on the O-H stretching vibration and O-H-O bending vibration of water molecules in the microscopic W/O micelles. FTIR spectra of the organic phase saturated with acids show that the broad band of O-H stretching vibration of water extended to a very wide range and overlaped with the C-H stretching vibration bands. The higher the acid concentration in the organic phase was, the greater the overlapping. On the other hand, it was also observed that a remarkable change appeared in the O-H-O bending vibration of water and the stretching vibration of PO in TBP molecules shifted to lower frequency. With the increase in acid content in the TBP organic phases, the observed 31P NMR chemical shifts decreased and varied to up-field; whereas the 1H NMR chemical shift of H+ increased and even became larger than that of deuterium chloride-d at a lower frequency field. The changes in ??P31 to opposite direction of ??H+ means that TBP molecules were associated with acid protons and water molecules in microemulsion pools to form RP=O·H+ or RP=O·H3O+, and then interacted with PdCl42- complex ions, which finally led to the extraction of palladium into the organic phase. (3) When forming the W/O reversed micelles/microemulsions, the concentration of acid within the microscopic micelles was even higher than that of saturated concentrated hydrochloric acid. It was the microscopic structural changes in organic phase microemulsion 'water pool' that resulted in the corresponding variations in the palladium extraction behaviors.; EI; 0; 9; 2038-2043; 28
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/408880]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Huang, Kun,Qi, Jian,Liu, Xue-Xin,et al. Formation of W/O microemulsions in TBP-Pd(II)-HCl extraction system and spectroscopic research on the evolution of solution aggregation structure[J]. guang pu xue yu guang pu fen xispectroscopy and spectral analysis,2008.
APA	Huang, Kun.,Qi, Jian.,Liu, Xue-Xin.,Liu, Yu-Feng.,Li, Wei-Hong.,...&Wu, Jin-Guang.(2008).Formation of W/O microemulsions in TBP-Pd(II)-HCl extraction system and spectroscopic research on the evolution of solution aggregation structure.guang pu xue yu guang pu fen xispectroscopy and spectral analysis.
MLA	Huang, Kun,et al."Formation of W/O microemulsions in TBP-Pd(II)-HCl extraction system and spectroscopic research on the evolution of solution aggregation structure".guang pu xue yu guang pu fen xispectroscopy and spectral analysis (2008).