Synthesis and X-ray crystal structure of   [Cd-2(OS(2)CSC(6)H(2)Bu(3)(t)-2,4,6)(4)(C2H5OH)(2)].C2H5OH. Disulfide   into Cd-S bonds

doi:10.1080/00958979508055398

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	Synthesis and X-ray crystal structure of [Cd-2(OS(2)CSC(6)H(2)Bu(3)(t)-2,4,6)(4)(C2H5OH)(2)].C2H5OH. Disulfide into Cd-S bonds
	Jin, XL ; Tang, KL ; Xia, TB ; Tang, YQ
刊名	journal of coordination chemistry
	1995
关键词	cadmium CS2 trithiocarbonate synthesis X-ray structure INSERTION REACTION CS2 PRODUCT
DOI	10.1080/00958979508055398
英文摘要	The title compound, C82H134Cd2O7S12, formed by reaction of the corresponding cadmium thiolate with CS2 and recrystallization from acetone/ethanol in air. Crystals belong to the triclinic space group , with Z = 2, cell dimensions a = 14.647(13), b = 19.140(20), c = 20.967(10)Angstrom, a = 64.79(6), beta = 79.56(5), gamma = 71.48(7)degrees, V = 5034 Angstrom(3). The structure was solved by direct methods and was refined to an R of 0.098 for 3754 observed reflections. All the Cd-S bonds were inserted by CS2, then the ligands were oxidized to form unusual ArSCS2O- groups. Cadmium atoms have distorted octahedral geometry. The distance between the two Cd atoms is 3.753 Angstrom.; Chemistry, Inorganic & Nuclear; SCI(E); 0; ARTICLE; 2; 187-194; 34
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/403055]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Jin, XL,Tang, KL,Xia, TB,et al. Synthesis and X-ray crystal structure of [Cd-2(OS(2)CSC(6)H(2)Bu(3)(t)-2,4,6)(4)(C2H5OH)(2)].C2H5OH. Disulfide into Cd-S bonds[J]. journal of coordination chemistry,1995.
APA	Jin, XL,Tang, KL,Xia, TB,&Tang, YQ.(1995).Synthesis and X-ray crystal structure of [Cd-2(OS(2)CSC(6)H(2)Bu(3)(t)-2,4,6)(4)(C2H5OH)(2)].C2H5OH. Disulfide into Cd-S bonds.journal of coordination chemistry.
MLA	Jin, XL,et al."Synthesis and X-ray crystal structure of [Cd-2(OS(2)CSC(6)H(2)Bu(3)(t)-2,4,6)(4)(C2H5OH)(2)].C2H5OH. Disulfide into Cd-S bonds".journal of coordination chemistry (1995).