SYNTHESIS AND CRYSTAL-STRUCTURE OF THE HETEROPOLYVANADATE ANION [ASV12O40(VO)2]9- | |
HUANG, GQ ; ZHANG, SW ; WEI, YG ; SHAO, MC | |
刊名 | polyhedron
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1993 | |
DOI | 10.1016/S0277-5387(00)84586-6 |
英文摘要 | The structure of (Et4N)3H6[AsV12O40(VO)2].20H2O has been determined by single-crystal X-ray diffraction analysis. In the anion the central AsO4 tetrahedron and 12VO6 octahedra form the usual Keggin structure (alpha-isomer) and the remaining two VO3+ groups occupy the cavities in the Keggin structure, where a two-fold axis passes to form trans-located tetragonal pyramidal caps.; Chemistry, Inorganic & Nuclear; Crystallography; SCI(E); 30; ARTICLE; 12; 1483-1485; 12 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/402219] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | HUANG, GQ,ZHANG, SW,WEI, YG,et al. SYNTHESIS AND CRYSTAL-STRUCTURE OF THE HETEROPOLYVANADATE ANION [ASV12O40(VO)2]9-[J]. polyhedron,1993. |
APA | HUANG, GQ,ZHANG, SW,WEI, YG,&SHAO, MC.(1993).SYNTHESIS AND CRYSTAL-STRUCTURE OF THE HETEROPOLYVANADATE ANION [ASV12O40(VO)2]9-.polyhedron. |
MLA | HUANG, GQ,et al."SYNTHESIS AND CRYSTAL-STRUCTURE OF THE HETEROPOLYVANADATE ANION [ASV12O40(VO)2]9-".polyhedron (1993). |
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