Study of the Rh-2(OAc)(4)- or BF3 center dot OEt2-mediated reaction of thioacetic S-Acid with alpha-diazocarbonyl compounds | |
Yao, WG ; Liao, MY ; Zhang, XM ; Xu, H ; Wang, JB | |
刊名 | 欧洲有机化学杂志
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2003 | |
关键词 | carbenoids diazo compounds insertion Lewis acids H INSERTION REACTIONS BETA-KETO-ESTERS O-H CARBENES SULFUR BOND |
DOI | 10.1002/ejoc.200200592 |
英文摘要 | The Rh-2(OAc)(4)-catalyzed reaction of methyl aryldiazo-acetates with thioacetic S-acid gives exclusively the S-H insertion products in high yields, while the corresponding reaction mediated by BF3.OEt2 gives O-esters. The mechanism,A the reaction is discussed. ((C) Wiley-VCH Vertag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000182789800025&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Organic; SCI(E); 15; ARTICLE; 9; 1784-1788 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/400765] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Yao, WG,Liao, MY,Zhang, XM,et al. Study of the Rh-2(OAc)(4)- or BF3 center dot OEt2-mediated reaction of thioacetic S-Acid with alpha-diazocarbonyl compounds[J]. 欧洲有机化学杂志,2003. |
APA | Yao, WG,Liao, MY,Zhang, XM,Xu, H,&Wang, JB.(2003).Study of the Rh-2(OAc)(4)- or BF3 center dot OEt2-mediated reaction of thioacetic S-Acid with alpha-diazocarbonyl compounds.欧洲有机化学杂志. |
MLA | Yao, WG,et al."Study of the Rh-2(OAc)(4)- or BF3 center dot OEt2-mediated reaction of thioacetic S-Acid with alpha-diazocarbonyl compounds".欧洲有机化学杂志 (2003). |
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