Synthesis and crystal structure of   {[HNEt3](2n)[Ag8Ag4/2(SC(6)H(4)tBu-4)(12)](n)center dot nC(2)H(5)OH} and   its reaction product with CS2

doi:10.1002/ejic.200300392

CORC > 北京大学 > 化学与分子工程学院

	Synthesis and crystal structure of {[HNEt3](2n)[Ag8Ag4/2(SC(6)H(4)tBu-4)(12)](n)center dot nC(2)H(5)OH} and its reaction product with CS2
	Tang, KL ; Xie, XJ ; Zhao, L ; Zhang, YH ; Jin, XL
刊名	欧洲无机化学杂志
	2004
关键词	silver polymers sulfur clusters SILVER CLUSTER COMPLEX X-RAY STRUCTURE LIGANDS CHEMISTRY SELENOLATE
DOI	10.1002/ejic.200300392
英文摘要	By using an arylthiolate ligand with a substituent in the paraposition, 4-tBuC(6)H(4)S(-), the yellow silver-thiolate complex {[hNEt(3)](2)[Ag8Ag4/2(SC(6)H(4)tBu-4)(12)](n).C2H5OH} (1) has been synthesized and structurally characterized. Complex 1 is ionic composed of [HNEt3](+) cations and a polymeric [Ag8Ag4/2(SC(6)H(4)tBu-4)(12)](n)(2n-) anion. Complex 1 reacts with CS2 in acetone to give a red pentaconta-nuclear silver anionic cluster complex {[HNEt3](4)[Ag50S7(SC(6)H(4)tBu-4)(40)].2CS(2).6C(3)H(6)O} (2). The core of the anionic cluster of 2 consists of fifty silver atoms and forty seven sulfur atoms, shaped like a discus with a diameter of ca. 2.0 nm. The factors influencing the structure and the formation mechanism of the large cluster are discussed. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004).; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000188531700008&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Inorganic & Nuclear; SCI(E); 19; ARTICLE; 1; 78-85
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/400519]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Tang, KL,Xie, XJ,Zhao, L,et al. Synthesis and crystal structure of {[HNEt3](2n)[Ag8Ag4/2(SC(6)H(4)tBu-4)(12)](n)center dot nC(2)H(5)OH} and its reaction product with CS2[J]. 欧洲无机化学杂志,2004.
APA	Tang, KL,Xie, XJ,Zhao, L,Zhang, YH,&Jin, XL.(2004).Synthesis and crystal structure of {[HNEt3](2n)[Ag8Ag4/2(SC(6)H(4)tBu-4)(12)](n)center dot nC(2)H(5)OH} and its reaction product with CS2.欧洲无机化学杂志.
MLA	Tang, KL,et al."Synthesis and crystal structure of {[HNEt3](2n)[Ag8Ag4/2(SC(6)H(4)tBu-4)(12)](n)center dot nC(2)H(5)OH} and its reaction product with CS2".欧洲无机化学杂志 (2004).