A comparative study of the optical and electroluminescent properties of   Eu-III complexes with TTA and 2-(2 &apos;-pyridyl)azoles: The crystal   structure of [Eu(TTA)3(PBO)]

CORC > 北京大学 > 化学与分子工程学院

	A comparative study of the optical and electroluminescent properties of Eu-III complexes with TTA and 2-(2 '-pyridyl)azoles: The crystal structure of [Eu(TTA)3(PBO)]
	Gao, Li-Hua ; Guan, Min ; Wang, Ke-Zhi ; Jin, Lin-Pei ; Huang, Chun-Hui
刊名	欧洲无机化学杂志
	2006
关键词	X-ray diffraction luminescence chelates N,O ligands lanthanides LANGMUIR-BLODGETT-FILM FUNCTIONALIZED EUROPIUM COMPLEX LANTHANIDE COMPLEXES RUTHENIUM(II) COMPLEX TERNARY COMPLEXES LUMINESCENT DEVICES LIGANDS DERIVATIVES ASSEMBLIES
英文摘要	Two Eu-III mixed-ligand complexes, namely [Eu(TTA)(3)(PBO)] and [Eu(TTA)(3)(PBT)] [TTA = 1,1,1-trifluoro-3-(2-thenoyl)acetonato, PBO = 2-(2'-pyridyl)-1,3-benzoxazole, and PBT = 2(2'-pyridyl)-1,3-benzothiazole], have been synthesized. [Eu(TTA)(3)(PBO)] has been structurally characterized by single-crystal X-ray diffraction analysis. The complex crystallizes in the monoclinic space group C2/c. The lattice parameters are a = 41.346(4), b = 10.0538(8), c = 20.3793(16) angstrom, beta = 110.922(2)degrees, Z = 8. The Eu-III ion is eight-coordinate, with three bidentate TTA(-) anions and one bidentate N,O-chelated PBO molecule. A comparative study by UV and emission spectroscopy was carried out and electroluminescent properties of the related complexes [Eu(TTA)(3)(PBO)] and [Eu-(TTA)(3)(PBT)] are reported as well. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006).; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000241010300024&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Inorganic & Nuclear; SCI(E); 19; ARTICLE; 18; 3731-3737
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/398350]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Gao, Li-Hua,Guan, Min,Wang, Ke-Zhi,et al. A comparative study of the optical and electroluminescent properties of Eu-III complexes with TTA and 2-(2 '-pyridyl)azoles: The crystal structure of [Eu(TTA)3(PBO)][J]. 欧洲无机化学杂志,2006.
APA	Gao, Li-Hua,Guan, Min,Wang, Ke-Zhi,Jin, Lin-Pei,&Huang, Chun-Hui.(2006).A comparative study of the optical and electroluminescent properties of Eu-III complexes with TTA and 2-(2 '-pyridyl)azoles: The crystal structure of [Eu(TTA)3(PBO)].欧洲无机化学杂志.
MLA	Gao, Li-Hua,et al."A comparative study of the optical and electroluminescent properties of Eu-III complexes with TTA and 2-(2 '-pyridyl)azoles: The crystal structure of [Eu(TTA)3(PBO)]".欧洲无机化学杂志 (2006).