1-lithio-1,3-dienes: Useful building blocks for cyclic compounds | |
Xi, Zhenfeng | |
刊名 | bulletin of the chemical society of japan |
2007 | |
关键词 | MULTIPLY SUBSTITUTED CYCLOPENTADIENES TEMPORARY SILICON CONNECTION PI-CONJUGATED SYSTEMS ANIONIC RING-CLOSURE EFFICIENT SYNTHESIS ELECTROPHILIC CYCLIZATION COUPLING REACTIONS 6-SUBSTITUTED PHENANTHRIDINES SYNTHETIC APPLICATIONS GROUP-14 METALLOLES |
DOI | 10.1246/bcsj.80.1021 |
英文摘要 | In this account, our recent results on the application of substituted 1-lithio-1,3-dienes as building blocks for the preparation of a wide variety of cyclic compounds and linear compounds are briefly summarized. Results have revealed that the essential factor which makes 1-lithio-1,3-diene derivatives useful and unique as building blocks is the intracooperation between the alkenyllithium moiety and the butadienyl skeleton, notwithstanding that the alkenyllithium moiety itself reacts with organic substrates in the usual way. In addition, the substitution patterns and the nature of the substituents on the butadienyl skeleton have been demonstrated to affect remarkably the reaction pathways of 1-lithio-1,3-diene derivatives.; Chemistry, Multidisciplinary; SCI(E); 0; REVIEW; 6; 1021-1032; 80 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/397833] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Xi, Zhenfeng. 1-lithio-1,3-dienes: Useful building blocks for cyclic compounds[J]. bulletin of the chemical society of japan,2007. |
APA | Xi, Zhenfeng.(2007).1-lithio-1,3-dienes: Useful building blocks for cyclic compounds.bulletin of the chemical society of japan. |
MLA | Xi, Zhenfeng."1-lithio-1,3-dienes: Useful building blocks for cyclic compounds".bulletin of the chemical society of japan (2007). |
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