Recent developments in copper-catalyzed reactions of diazo compounds | |
Zhao, Xia ; Zhang, Yan ; Wang, Jianbo | |
刊名 | chemical communications |
2012 | |
关键词 | H INSERTION REACTIONS HIGHLY ENANTIOSELECTIVE INSERTION ALPHA-DIAZOCARBONYL COMPOUNDS MEDIATED DIRECT ARYLATION ORGANIC-SYNTHESIS CYCLOPROPANATION REACTIONS 3-COMPONENT REACTION CARBENOID INSERTION TERMINAL ALKYNES SULFUR YLIDES |
DOI | 10.1039/c2cc34406h |
英文摘要 | Copper-catalyzed reaction of diazo compounds generates copper carbene intermediates that undergo diverse transformations. In recent years, the selectivity and efficiency of these important conversions have been further improved. In particular, breakthroughs have been made in catalytic asymmetric polar X-H bond insertion reactions. Moreover, novel transformations based on copper carbene, namely copper-catalyzed cross-couplings of diazo compounds, have emerged as powerful methods for carbon-carbon bond formations. This feature article summarizes the most recent developments in this area.; Chemistry, Multidisciplinary; SCI(E); 50; ARTICLE; 82; 10162-10173; 48 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/393873] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Zhao, Xia,Zhang, Yan,Wang, Jianbo. Recent developments in copper-catalyzed reactions of diazo compounds[J]. chemical communications,2012. |
APA | Zhao, Xia,Zhang, Yan,&Wang, Jianbo.(2012).Recent developments in copper-catalyzed reactions of diazo compounds.chemical communications. |
MLA | Zhao, Xia,et al."Recent developments in copper-catalyzed reactions of diazo compounds".chemical communications (2012). |
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