VIBRATIONAL SPECTRA OF HYDROUS MANGANESE SALT 18-CROWN-6 COMPOUNDS | |
Liang Yingqiu ; Lin Yinzhang ; Wu Jinguang ; Xu Guangxian | |
刊名 | 物理化学学报
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1989 | |
DOI | 10.3866/PKU.WHXB19890523 |
英文摘要 | The componds with molecular formula Mn(NCS)(2)center dot 4H(2)O center dot 18C(6) and (Mn2Cl center dot 8H(2)O)center dot 18C(6) center dot 2Cl were synthesize and their FT-IR, Raman spectra were measured over region of 4000-100 cm(-1). The vibrational spectra show that in both compounds the Mn2+ ion are not coordinated to 18C5 but combined with 18C6 by hydrogen bonds orginated from the hydrous water of manganese. In addition, by means of the changes of vibration for crown ether ring in IR together with that the appeanrence of a band near 867 cm(-1), which belongs to the breath vibration of ring, or not, one can predicate that the transition element crown compound with a single nucleus or a long chain structure.; Chemistry, Physical; SCI(E); 中国科学引文数据库(CSCD); 0; 5; 621-625; 5 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/390331] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Liang Yingqiu,Lin Yinzhang,Wu Jinguang,et al. VIBRATIONAL SPECTRA OF HYDROUS MANGANESE SALT 18-CROWN-6 COMPOUNDS[J]. 物理化学学报,1989. |
APA | Liang Yingqiu,Lin Yinzhang,Wu Jinguang,&Xu Guangxian.(1989).VIBRATIONAL SPECTRA OF HYDROUS MANGANESE SALT 18-CROWN-6 COMPOUNDS.物理化学学报. |
MLA | Liang Yingqiu,et al."VIBRATIONAL SPECTRA OF HYDROUS MANGANESE SALT 18-CROWN-6 COMPOUNDS".物理化学学报 (1989). |
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